Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand:Synthesis, Crystal Structure and Magnetic Property

ISL OpenIR > 青海盐湖研究所知识仓储

	Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand:Synthesis, Crystal Structure and Magnetic Property
	Zhao, Yang; Zhang, Suyun; Zheng, Lina; Li, Yahong
	2011
发表期刊	ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
卷号	637 期号:10 页码:1304-1307
关键词	2-pyridyloximate Tetranuclear Complexes Manganese Ir Spectroscopy
摘要	A tetranuclear manganese complex of the composition {Mn(4)[(Py)C(Ph)NO](4)(CH(3)CH(2)OH)(3)(CH(3)CH(2)O)Cl(3)}center dot 2H(2)O (1) was synthesized by solvothermal reaction, and characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. X-ray analysis revealed that complex 1 contains a [Mn(4)(NO)(4)](4+) core with three Mn(II) atoms displaying distorted octahedral arrangements and one Mn(II) ion exhibiting a trigonal bipyramidal arrangement. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed antiferromagnetic Mn(II)center dot center dot center dot Mn(II) interactions. A tetranuclear manganese complex of the composition {Mn(4)[(Py)C(Ph)NO](4)(CH(3)CH(2)OH)(3)(CH(3)CH(2)O)Cl(3)}center dot 2H(2)O (1) was synthesized by solvothermal reaction, and characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. X-ray analysis revealed that complex 1 contains a [Mn(4)(NO)(4)](4+) core with three Mn(II) atoms displaying distorted octahedral arrangements and one Mn(II) ion exhibiting a trigonal bipyramidal arrangement. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed antiferromagnetic Mn(II)center dot center dot center dot Mn(II) interactions.
语种	英语
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/1889
专题	青海盐湖研究所知识仓储
推荐引用方式 GB/T 7714	Zhao, Yang,Zhang, Suyun,Zheng, Lina,et al. Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand:Synthesis, Crystal Structure and Magnetic Property[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2011,637(10):1304-1307.
APA	Zhao, Yang,Zhang, Suyun,Zheng, Lina,&Li, Yahong.(2011).Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand:Synthesis, Crystal Structure and Magnetic Property.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,637(10),1304-1307.
MLA	Zhao, Yang,et al."Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand:Synthesis, Crystal Structure and Magnetic Property".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 637.10(2011):1304-1307.

条目包含的文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
1304_ftp[1].pdf（326KB）			开放获取	CC BY-NC-SA	浏览请求全文