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Experimental design in the analysis of interferential effects for thedetermination of Sr in high Ca/Sr ratio brine by inductively coupledplasma atomic emission spectroscopy technique
Xu, Bin; Gao, Dandan; Dong, Yaping; Li, Wu; Li, Yahong
2011
发表期刊INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
卷号91期号:3页码:291-301
关键词Experimental Design Strontium High Ca Sr Ratio Brine Inductively
摘要The ICP-AES technique and experimental design were employed to precisely determine the content of strontium in high Ca/Sr ratio oil field brine of Qaidam basin (Qinghai province, western China). From the statistical analysis using six factor factorial, it was found that Ca2+ is the significant interfering element for the recovery of strontium. Accurate strontium content was derived by eliminating the interference contribution according to the influencing model. The experimental results indicate that, under optimal conditions, the ICP-AES method for strontium determination has low LOD and LOQ, and the precision and accuracy are good with the relatively standard deviation below 1% and recovery between 98.0% 105.0%. The ICP-AES technique and experimental design were employed to precisely determine the content of strontium in high Ca/Sr ratio oil field brine of Qaidam basin (Qinghai province, western China). From the statistical analysis using six factor factorial, it was found that Ca2+ is the significant interfering element for the recovery of strontium. Accurate strontium content was derived by eliminating the interference contribution according to the influencing model. The experimental results indicate that, under optimal conditions, the ICP-AES method for strontium determination has low LOD and LOQ, and the precision and accuracy are good with the relatively standard deviation below 1% and recovery between 98.0% 105.0%.
语种英语
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/1890
专题青海盐湖研究所知识仓储
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GB/T 7714
Xu, Bin,Gao, Dandan,Dong, Yaping,et al. Experimental design in the analysis of interferential effects for thedetermination of Sr in high Ca/Sr ratio brine by inductively coupledplasma atomic emission spectroscopy technique[J]. INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY,2011,91(3):291-301.
APA Xu, Bin,Gao, Dandan,Dong, Yaping,Li, Wu,&Li, Yahong.(2011).Experimental design in the analysis of interferential effects for thedetermination of Sr in high Ca/Sr ratio brine by inductively coupledplasma atomic emission spectroscopy technique.INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY,91(3),291-301.
MLA Xu, Bin,et al."Experimental design in the analysis of interferential effects for thedetermination of Sr in high Ca/Sr ratio brine by inductively coupledplasma atomic emission spectroscopy technique".INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY 91.3(2011):291-301.
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