Titanium amido- and imido-complexes supported by a tridentate pyrrolylligand: syntheses, characterisation and catalytic activities

ISL OpenIR > 青海盐湖研究所知识仓储

	Titanium amido- and imido-complexes supported by a tridentate pyrrolylligand: syntheses, characterisation and catalytic activities
	Chen, Zhou; Li, Lei; Chen, Yanmei; Hu, Bin; Wu, Jian; Wang, Xiufang; Lei, Tao; Li, Yahong
	2012
发表期刊	JOURNAL OF CHEMICAL RESEARCH
ISSN	1747-5198
期号	5 页码:249-253
关键词	Titanium Imines X-ray Structure Hydroamination
摘要	The complexes [Ti(NMe2)(2)(pmpmi)][H(2)pmpmi = (2-pyrrolylmethene)-(2-pyrrolylmethyl)imine], [Ti((NBu)-Bu-t)(pmpmi)(py)(2)], [Ti((NBu)-Bu-t)(pmpmi)(dpy)] and [Ti(NPh)(pmpmi)(py)(2)] have been prepared, characterised and shown to be pre-catalysts for the hydroamination of phenylacetylene with aniline and p-chloroaniline. The X-ray structures of (Ti(NMe2)(2)(pmpmi)], [Ti((NBu)-Bu-t)(pmpmi)(dpy)] and (Ti(NPh)(pmpmi)(py)(2)] have been determined. The complexes [Ti(NMe2)(2)(pmpmi)][H(2)pmpmi = (2-pyrrolylmethene)-(2-pyrrolylmethyl)imine], [Ti((NBu)-Bu-t)(pmpmi)(py)(2)], [Ti((NBu)-Bu-t)(pmpmi)(dpy)] and [Ti(NPh)(pmpmi)(py)(2)] have been prepared, characterised and shown to be pre-catalysts for the hydroamination of phenylacetylene with aniline and p-chloroaniline. The X-ray structures of (Ti(NMe2)(2)(pmpmi)], [Ti((NBu)-Bu-t)(pmpmi)(dpy)] and (Ti(NPh)(pmpmi)(py)(2)] have been determined.
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/2053
专题	青海盐湖研究所知识仓储
推荐引用方式 GB/T 7714	Chen, Zhou,Li, Lei,Chen, Yanmei,et al. Titanium amido- and imido-complexes supported by a tridentate pyrrolylligand: syntheses, characterisation and catalytic activities[J]. JOURNAL OF CHEMICAL RESEARCH,2012(5):249-253.
APA	Chen, Zhou.,Li, Lei.,Chen, Yanmei.,Hu, Bin.,Wu, Jian.,...&Li, Yahong.(2012).Titanium amido- and imido-complexes supported by a tridentate pyrrolylligand: syntheses, characterisation and catalytic activities.JOURNAL OF CHEMICAL RESEARCH(5),249-253.
MLA	Chen, Zhou,et al."Titanium amido- and imido-complexes supported by a tridentate pyrrolylligand: syntheses, characterisation and catalytic activities".JOURNAL OF CHEMICAL RESEARCH .5(2012):249-253.