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Spectral studies of novel Na specific adsorbent Li1+xAlxTi2-x(PO4)(3)
Sun Jian-zhi; Deng Xiao-chuan; Song Shi-tao; Wei Shu-bin; Ma Pei-hua
2006-10-01
发表期刊SPECTROSCOPY AND SPECTRAL ANALYSIS
ISSN1000-0593
卷号26期号:10页码:1943-1947
关键词Adsorbent Li-contained Phosphates X-ray Diffraction Ir Spectrum Raman Spectrum
摘要A novel Na. specific adsorbent Li1+xAlxTi2-x(PO4)(3) was synthesized by high temperature solid state reaction method. The samples were characterized by X-ray diffraction(XRD) and scanning electron microseope(SEM). Raman and FTIR spectroscopic studies of these materials were carried out, and the vibrational bands were assigned. Their adsorption performances were investigated. The results indicate that the low concentration(x < 0.6) Al dopant does not affect the structure of the material but makes it able to selectively adsorb sodium The adsorbing test results show that its exchange capacity is high with the maximum value of adsorption capacity of 11.76 mg center dot g(-1) at x = 0.4 and pH 10.0-11.0. So it can be used to remove the microamounts impurity-sodium in the production of high purity lithium salt. A novel Na. specific adsorbent Li1+xAlxTi2-x(PO4)(3) was synthesized by high temperature solid state reaction method. The samples were characterized by X-ray diffraction(XRD) and scanning electron microseope(SEM). Raman and FTIR spectroscopic studies of these materials were carried out, and the vibrational bands were assigned. Their adsorption performances were investigated. The results indicate that the low concentration(x < 0.6) Al dopant does not affect the structure of the material but makes it able to selectively adsorb sodium The adsorbing test results show that its exchange capacity is high with the maximum value of adsorption capacity of 11.76 mg center dot g(-1) at x = 0.4 and pH 10.0-11.0. So it can be used to remove the microamounts impurity-sodium in the production of high purity lithium salt.; A novel Na. specific adsorbent Li1+xAlxTi2-x(PO4)(3) was synthesized by high temperature solid state reaction method. The samples were characterized by X-ray diffraction(XRD) and scanning electron microseope(SEM). Raman and FTIR spectroscopic studies of these materials were carried out, and the vibrational bands were assigned. Their adsorption performances were investigated. The results indicate that the low concentration(x < 0.6) Al dopant does not affect the structure of the material but makes it able to selectively adsorb sodium The adsorbing test results show that its exchange capacity is high with the maximum value of adsorption capacity of 11.76 mg center dot g(-1) at x = 0.4 and pH 10.0-11.0. So it can be used to remove the microamounts impurity-sodium in the production of high purity lithium salt.
语种英语
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/2307
专题中国科学院青海盐湖研究所
盐湖资源综合利用工程技术中心
青海盐湖研究所知识仓储
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Sun Jian-zhi,Deng Xiao-chuan,Song Shi-tao,et al. Spectral studies of novel Na specific adsorbent Li1+xAlxTi2-x(PO4)(3)[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2006,26(10):1943-1947.
APA Sun Jian-zhi,Deng Xiao-chuan,Song Shi-tao,Wei Shu-bin,&Ma Pei-hua.(2006).Spectral studies of novel Na specific adsorbent Li1+xAlxTi2-x(PO4)(3).SPECTROSCOPY AND SPECTRAL ANALYSIS,26(10),1943-1947.
MLA Sun Jian-zhi,et al."Spectral studies of novel Na specific adsorbent Li1+xAlxTi2-x(PO4)(3)".SPECTROSCOPY AND SPECTRAL ANALYSIS 26.10(2006):1943-1947.
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