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Study on preparation and properties of novel Na+ specific adsorbentLi1+xLaxZr2-x(PO4)(3) | |
Sun, JZ; Ma, PH; Deng, XC![]() | |
2006 | |
发表期刊 | ACTA CHIMICA SINICA
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ISSN | 0567-7351 |
卷号 | 64期号:2页码:182-186 |
摘要 | A series of novel kind of Na+ specific adsorbent compounds Li1+xLaxZr2-x(PO4)(3) were synthesized by high temperature solid state reaction method. The samples were characterized by XRD, SEM, IR techniques and their adsorption performances were investigated. XRD analysis showed that a structure of LiZr2(PO4)(3) could be found in the composition range of x <= 0.4. SEM analysis showed that they were highly dispersive particles with diameters of 5 similar to 20 mu m. The investigation of the adsorption properties showed that the low concentration La dopant (x <= 0.4) made it adsorb sodium selectively, and also confirmed that the La ion dopant was an effective method to improve the adsorption properties. The exchange capacity was 48.3 mg/g, under x=0.4, pH=10.0 similar to 11.0 in LiCl solution. A series of novel kind of Na+ specific adsorbent compounds Li1+xLaxZr2-x(PO4)(3) were synthesized by high temperature solid state reaction method. The samples were characterized by XRD, SEM, IR techniques and their adsorption performances were investigated. XRD analysis showed that a structure of LiZr2(PO4)(3) could be found in the composition range of x <= 0.4. SEM analysis showed that they were highly dispersive particles with diameters of 5 similar to 20 mu m. The investigation of the adsorption properties showed that the low concentration La dopant (x <= 0.4) made it adsorb sodium selectively, and also confirmed that the La ion dopant was an effective method to improve the adsorption properties. The exchange capacity was 48.3 mg/g, under x=0.4, pH=10.0 similar to 11.0 in LiCl solution. |
文献类型 | 期刊论文 |
条目标识符 | http://ir.isl.ac.cn/handle/363002/2315 |
专题 | 青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
推荐引用方式 GB/T 7714 | Sun, JZ,Ma, PH,Deng, XC,et al. Study on preparation and properties of novel Na+ specific adsorbentLi1+xLaxZr2-x(PO4)(3)[J]. ACTA CHIMICA SINICA,2006,64(2):182-186. |
APA | Sun, JZ,Ma, PH,Deng, XC,Song, ST,Yan, CY,&Wei, SB.(2006).Study on preparation and properties of novel Na+ specific adsorbentLi1+xLaxZr2-x(PO4)(3).ACTA CHIMICA SINICA,64(2),182-186. |
MLA | Sun, JZ,et al."Study on preparation and properties of novel Na+ specific adsorbentLi1+xLaxZr2-x(PO4)(3)".ACTA CHIMICA SINICA 64.2(2006):182-186. |
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