Synthesis, characterization, and amine intercalation behavior ofzirconium N-(phosphonomethyl)iminodiacetic acid layered compounds

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	Synthesis, characterization, and amine intercalation behavior ofzirconium N-(phosphonomethyl)iminodiacetic acid layered compounds
	Zhang, BL; Poojary, DM; Clearfield, A; Peng, GZ
	1996
发表期刊	CHEMISTRY OF MATERIALS
ISSN	0897-4756
卷号	8 期号:6 页码:1333-1340
摘要	New types of zirconium layered compounds containing the N-(phosphonomethyl)iminodiacetic acid group (PMIDAH(2)) have been synthesized and characterized. A mixed phosphate/ phosphonate compound, Zr-2(PO4)(O3PCH2N{CH2COOH}(2))(O3PCH2N{CH2-COO-})(H2O)(2) (I) was obtained when a mixture of phosphoric acid adn diacetatoiminophosphonic acid (H(2)PMIDAH(2)) solution in the ratio of 1:1 was heated with the zirconyl chloride in the presence of HF. The layer structure of this compound is different from that of any known layered zirconium phosphonate compounds. The bridging of metal atoms by the phosphate groups within the layer is similar to that found in gamma-ZrP, while the mode of phosphonate binding is similar to that found for alpha-ZrP. When the above reaction was carried out with additional phosphoric acid, a similar layered structure but with composition Zr-2(PO4)(O3PC5H7O4N)(O3PC5H8O4N)(x)(HPO4)(1-x)(H2O)(2) (II) was obtained. In this compound some of the phosphonate groups are replaced by the HPO42- groups. When the ratio of phosphoric acid to H(2)PMIDAH(2) was 4, the compound obtained has the maximum replacement. The value of x for this compound in the above formula is 0.5. Further addition of phosphonic acid yields a new phase with composition Zr(O3PC5H8O4N)(x)(HPO4)(1-x), (III). P-31 solid-state MAS NMR and XRD patterns suggest that this new phase is structurally similar to alpha-ZrP. Intercalation reactions with primary alkylamines, CnH2n+1NH2 (n = 3-8), were carried out with all these phases. The results show that 2 mol of amines were taken up by compound I to form [Zr-2(Po-4)(PMIDAH(2))(PMIDAH)(H2O)(2)]. 2RNH(2), while 1.5 mol of amine was intercalated into compound III, forming Zr(PMIDAH(2))(x)(HPO4)(1-x). 1.5RNH(2). In both compounds the amines appear to pack as double layers. The ion-exchange behavior of these compounds is also discussed. New types of zirconium layered compounds containing the N-(phosphonomethyl)iminodiacetic acid group (PMIDAH(2)) have been synthesized and characterized. A mixed phosphate/ phosphonate compound, Zr-2(PO4)(O3PCH2N{CH2COOH}(2))(O3PCH2N{CH2-COO-})(H2O)(2) (I) was obtained when a mixture of phosphoric acid adn diacetatoiminophosphonic acid (H(2)PMIDAH(2)) solution in the ratio of 1:1 was heated with the zirconyl chloride in the presence of HF. The layer structure of this compound is different from that of any known layered zirconium phosphonate compounds. The bridging of metal atoms by the phosphate groups within the layer is similar to that found in gamma-ZrP, while the mode of phosphonate binding is similar to that found for alpha-ZrP. When the above reaction was carried out with additional phosphoric acid, a similar layered structure but with composition Zr-2(PO4)(O3PC5H7O4N)(O3PC5H8O4N)(x)(HPO4)(1-x)(H2O)(2) (II) was obtained. In this compound some of the phosphonate groups are replaced by the HPO42- groups. When the ratio of phosphoric acid to H(2)PMIDAH(2) was 4, the compound obtained has the maximum replacement. The value of x for this compound in the above formula is 0.5. Further addition of phosphonic acid yields a new phase with composition Zr(O3PC5H8O4N)(x)(HPO4)(1-x), (III). P-31 solid-state MAS NMR and XRD patterns suggest that this new phase is structurally similar to alpha-ZrP. Intercalation reactions with primary alkylamines, CnH2n+1NH2 (n = 3-8), were carried out with all these phases. The results show that 2 mol of amines were taken up by compound I to form [Zr-2(Po-4)(PMIDAH(2))(PMIDAH)(H2O)(2)]. 2RNH(2), while 1.5 mol of amine was intercalated into compound III, forming Zr(PMIDAH(2))(x)(HPO4)(1-x). 1.5RNH(2). In both compounds the amines appear to pack as double layers. The ion-exchange behavior of these compounds is also discussed.
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/2391
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
推荐引用方式 GB/T 7714	Zhang, BL,Poojary, DM,Clearfield, A,et al. Synthesis, characterization, and amine intercalation behavior ofzirconium N-(phosphonomethyl)iminodiacetic acid layered compounds[J]. CHEMISTRY OF MATERIALS,1996,8(6):1333-1340.
APA	Zhang, BL,Poojary, DM,Clearfield, A,&Peng, GZ.(1996).Synthesis, characterization, and amine intercalation behavior ofzirconium N-(phosphonomethyl)iminodiacetic acid layered compounds.CHEMISTRY OF MATERIALS,8(6),1333-1340.
MLA	Zhang, BL,et al."Synthesis, characterization, and amine intercalation behavior ofzirconium N-(phosphonomethyl)iminodiacetic acid layered compounds".CHEMISTRY OF MATERIALS 8.6(1996):1333-1340.