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Study on teh Reaction Thermochemistry of Simulated Synthesized Brineduring Hydrocholoric Acid Titration
Li, W; Gao, SY; Zeng, ZM; Xin, SP
1995
发表期刊ACTA PHYSICO-CHIMICA SINICA
ISSN1000-6818
卷号11期号:12页码:1101-1104
摘要The enthalpy changes of MgO center dot 2B(2)O(3)-27.56% MgCl(2)-H(2)O and H(3)BO(3)center dot 27.56% MgCl(2)-H(2)O slution durin g azeotropic hydrocholoric acid titration have been studied with Sweden LKB8700-1 precise calorimeter. The results indicated that the reaction enthalpy changes of solutes (expressed as H(3)BO(3) and MgO center dot 2B(2)O(3)) increase with the increase of their concentrations ini the solution. Combined with the pH titration curves of MgO center dot 2B(2)O(3)-27.56% MgCl(2)-H(2)O with that of azeotropic hydrochloric acid, the reactino mechanism of the solutions with hydrochloric acid has been discussed. The enthalpy changes of MgO center dot 2B(2)O(3)-27.56% MgCl(2)-H(2)O and H(3)BO(3)center dot 27.56% MgCl(2)-H(2)O slution durin g azeotropic hydrocholoric acid titration have been studied with Sweden LKB8700-1 precise calorimeter. The results indicated that the reaction enthalpy changes of solutes (expressed as H(3)BO(3) and MgO center dot 2B(2)O(3)) increase with the increase of their concentrations ini the solution. Combined with the pH titration curves of MgO center dot 2B(2)O(3)-27.56% MgCl(2)-H(2)O with that of azeotropic hydrochloric acid, the reactino mechanism of the solutions with hydrochloric acid has been discussed.
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/2406
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
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GB/T 7714
Li, W,Gao, SY,Zeng, ZM,et al. Study on teh Reaction Thermochemistry of Simulated Synthesized Brineduring Hydrocholoric Acid Titration[J]. ACTA PHYSICO-CHIMICA SINICA,1995,11(12):1101-1104.
APA Li, W,Gao, SY,Zeng, ZM,&Xin, SP.(1995).Study on teh Reaction Thermochemistry of Simulated Synthesized Brineduring Hydrocholoric Acid Titration.ACTA PHYSICO-CHIMICA SINICA,11(12),1101-1104.
MLA Li, W,et al."Study on teh Reaction Thermochemistry of Simulated Synthesized Brineduring Hydrocholoric Acid Titration".ACTA PHYSICO-CHIMICA SINICA 11.12(1995):1101-1104.
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