| Extraction and separation of lithium isotopes by using organic liquid film extraction system of crown ether-ionic liquid | |
Zhang, Zezheng; Jia, Yongzhong ; Liu, Bing; Sun, Huaxin; Jing, Yan; Zhang, Quanyou; Shao, Fei; Qi, Mixiang; Yao, Ying
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| 第一作者 | Zhang, Zezheng |
| 2020-12 | |
| 发表期刊 | FUSION ENGINEERING AND DESIGN
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| ISSN | 0920-3796 |
| 卷号 | 161 |
| 摘要 | The organic liquid film extraction system, a novel extraction system, was investigated for the extraction and separation of lithium isotopes using ionic liquid as the co-extractant and Dibenzo-15-crown 5-Ether (DB15C5) as the extractant. Multiple subjects were studied during the investigation, including the effects of extraction time; gas flow rate; temperature; counter anions of lithium salt; the length of the cationic carbon chain of ionic liquid on extraction, and separation of lithium isotopes. The maximum separation factor alpha was 1.037 +/- 0.002 and the abundance of Li-6 increased from 7.61 % to 7.86 %. Based on the slope analysis method, the formation of 1:1 complex [Li (DB15C5)](+) in the extraction phase was determined. The exchange of lithium isotope is spontaneous reaction at low temperatures (Delta H<0, Delta S<0). Also, the back-extraction times of lithium ions from extraction phase to aqueous phase were studied. |
| DOI | 10.1016/j.fusengdes.2020.112015 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.isl.ac.cn/handle/363002/33966 |
| 专题 | 盐湖资源综合利用工程技术中心 中国科学院青海盐湖研究所 |
| 推荐引用方式 GB/T 7714 | Zhang, Zezheng,Jia, Yongzhong,Liu, Bing,et al. Extraction and separation of lithium isotopes by using organic liquid film extraction system of crown ether-ionic liquid[J]. FUSION ENGINEERING AND DESIGN,2020,161. |
| APA | Zhang, Zezheng.,Jia, Yongzhong.,Liu, Bing.,Sun, Huaxin.,Jing, Yan.,...&Yao, Ying.(2020).Extraction and separation of lithium isotopes by using organic liquid film extraction system of crown ether-ionic liquid.FUSION ENGINEERING AND DESIGN,161. |
| MLA | Zhang, Zezheng,et al."Extraction and separation of lithium isotopes by using organic liquid film extraction system of crown ether-ionic liquid".FUSION ENGINEERING AND DESIGN 161(2020). |
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| Extraction and separ（2348KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | 浏览 请求全文 | |
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