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Synthesis, Crystal Structure, and Thermal Property of a Potassium-ammonium Double Salt K-0.48(NH4)(0.52)MgCl3 center dot 6H(2)O
Yang, Hongjun; Chen, Yanmei; Wang, Min; Li, Bing
2019-03
发表期刊CRYSTALLOGRAPHY REPORTS
ISSN1063-7745
卷号64期号:2页码:277-281
摘要By evaporating the brine containing potassium and ammonium cations compound of the composition K-0.48(NH4)(0.52)MgCl3 6H(2)O was obtained. Its crystal structure was determined by single crystal X-ray analysis. In the crystal, monovalent cation consists of 52% of ammonium and 48% of potassium. The crystal structure consists of a network of (N,K)Cl-6 octahedra and Mg(H2O)(6) octahedra occupying the cavities in this network. Its unit cell parameters are similar to those of ammonium carnallite. There are obvious differences between the crystal structure of carnallite and the compound. IR spectra show that both carnallite and ammonium chloride characteristic peaks are detected. The thermal behaviour was also investigated.
DOI10.1134/S1063774519020135
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/34090
专题盐湖资源与化学实验室
中国科学院青海盐湖研究所
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Yang, Hongjun,Chen, Yanmei,Wang, Min,et al. Synthesis, Crystal Structure, and Thermal Property of a Potassium-ammonium Double Salt K-0.48(NH4)(0.52)MgCl3 center dot 6H(2)O[J]. CRYSTALLOGRAPHY REPORTS,2019,64(2):277-281.
APA Yang, Hongjun,Chen, Yanmei,Wang, Min,&Li, Bing.(2019).Synthesis, Crystal Structure, and Thermal Property of a Potassium-ammonium Double Salt K-0.48(NH4)(0.52)MgCl3 center dot 6H(2)O.CRYSTALLOGRAPHY REPORTS,64(2),277-281.
MLA Yang, Hongjun,et al."Synthesis, Crystal Structure, and Thermal Property of a Potassium-ammonium Double Salt K-0.48(NH4)(0.52)MgCl3 center dot 6H(2)O".CRYSTALLOGRAPHY REPORTS 64.2(2019):277-281.
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