Solid-Liquid Stable Equilibrium of the Quaternary System LiCl + NaCl + Li2SO4 + Na2SO4 + H2O at 288.15 K

doi:10.1007/s10953-021-01107-1

	Solid-Liquid Stable Equilibrium of the Quaternary System LiCl + NaCl + Li2SO4 + Na2SO4 + H2O at 288.15 K
	Zhang, Yong-Ming; Cui, Rui-Zhi; Dong, Ya-Ping; Li, Wu
第一作者	Zhang, Yong-Ming
	2021-08
发表期刊	JOURNAL OF SOLUTION CHEMISTRY
ISSN	0095-9782
卷号	50 期号:8 页码:1103-1112
摘要	In this study, the isothermal saturation method was applied to obtain the data for solid-liquid equilibria in a system consisting of four solids (LiCl + NaCl + Li2SO4 + Na2SO4) and water at 288.15 K. The chemical composition of the liquid phase was experimentally determined, and the corresponding phase diagrams were constructed. The obtained diagram exhibited 6 crystallization areas, 10 univariant curves, and 5 invariant points. The 6 crystallization regions consisted of LiCl center dot 2H(2)O, Li2SO4 center dot H2O, NaCl, Na2SO4 center dot 10H(2)O, Li2SO4 center dot 3Na(2)SO(4)center dot 12H(2)O and Li2SO4 center dot Na2SO4. The solid-phase solubilities and phase equilibria were derived from the experimental data at 288.15 K using Pitzer's equations. The calculated data were compared with the experiment, and the corresponding phase diagrams for both datasets were calculated. Experimental and theoretical diagrams were in good agreement.
DOI	10.1007/s10953-021-01107-1
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/34185
专题	盐湖资源综合利用工程技术中心
推荐引用方式 GB/T 7714	Zhang, Yong-Ming,Cui, Rui-Zhi,Dong, Ya-Ping,et al. Solid-Liquid Stable Equilibrium of the Quaternary System LiCl + NaCl + Li2SO4 + Na2SO4 + H2O at 288.15 K[J]. JOURNAL OF SOLUTION CHEMISTRY,2021,50(8):1103-1112.
APA	Zhang, Yong-Ming,Cui, Rui-Zhi,Dong, Ya-Ping,&Li, Wu.(2021).Solid-Liquid Stable Equilibrium of the Quaternary System LiCl + NaCl + Li2SO4 + Na2SO4 + H2O at 288.15 K.JOURNAL OF SOLUTION CHEMISTRY,50(8),1103-1112.
MLA	Zhang, Yong-Ming,et al."Solid-Liquid Stable Equilibrium of the Quaternary System LiCl + NaCl + Li2SO4 + Na2SO4 + H2O at 288.15 K".JOURNAL OF SOLUTION CHEMISTRY 50.8(2021):1103-1112.

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