Solid-Liquid Stable Equilibrium of the Quaternary System LiCl + NaCl + Li2SO4 + Na2SO4 + H2O at 288.15 K | |
Zhang, Yong-Ming; Cui, Rui-Zhi; Dong, Ya-Ping; Li, Wu | |
第一作者 | Zhang, Yong-Ming |
2021-08 | |
发表期刊 | JOURNAL OF SOLUTION CHEMISTRY |
ISSN | 0095-9782 |
卷号 | 50期号:8页码:1103-1112 |
摘要 | In this study, the isothermal saturation method was applied to obtain the data for solid-liquid equilibria in a system consisting of four solids (LiCl + NaCl + Li2SO4 + Na2SO4) and water at 288.15 K. The chemical composition of the liquid phase was experimentally determined, and the corresponding phase diagrams were constructed. The obtained diagram exhibited 6 crystallization areas, 10 univariant curves, and 5 invariant points. The 6 crystallization regions consisted of LiCl center dot 2H(2)O, Li2SO4 center dot H2O, NaCl, Na2SO4 center dot 10H(2)O, Li2SO4 center dot 3Na(2)SO(4)center dot 12H(2)O and Li2SO4 center dot Na2SO4. The solid-phase solubilities and phase equilibria were derived from the experimental data at 288.15 K using Pitzer's equations. The calculated data were compared with the experiment, and the corresponding phase diagrams for both datasets were calculated. Experimental and theoretical diagrams were in good agreement. |
DOI | 10.1007/s10953-021-01107-1 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.isl.ac.cn/handle/363002/34185 |
专题 | 盐湖资源综合利用工程技术中心 |
推荐引用方式 GB/T 7714 | Zhang, Yong-Ming,Cui, Rui-Zhi,Dong, Ya-Ping,et al. Solid-Liquid Stable Equilibrium of the Quaternary System LiCl + NaCl + Li2SO4 + Na2SO4 + H2O at 288.15 K[J]. JOURNAL OF SOLUTION CHEMISTRY,2021,50(8):1103-1112. |
APA | Zhang, Yong-Ming,Cui, Rui-Zhi,Dong, Ya-Ping,&Li, Wu.(2021).Solid-Liquid Stable Equilibrium of the Quaternary System LiCl + NaCl + Li2SO4 + Na2SO4 + H2O at 288.15 K.JOURNAL OF SOLUTION CHEMISTRY,50(8),1103-1112. |
MLA | Zhang, Yong-Ming,et al."Solid-Liquid Stable Equilibrium of the Quaternary System LiCl + NaCl + Li2SO4 + Na2SO4 + H2O at 288.15 K".JOURNAL OF SOLUTION CHEMISTRY 50.8(2021):1103-1112. |
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