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Electromigration of [C6MIm][TFSI]from Ionic Liquids Bulk to Aqueous Solutions
王明勇; 孙进贺; 张鹏瑞; 黄超驰; 张茜; 邵斐; 景燕; 贾永忠
FirstAuthor王明勇
2021-06-15
Source Publication盐湖研究
ISSN1008-858X
Volume29Issue:02Pages:35-43
Keyword离子液体 电迁移 电极水溶液 回溶
Abstract离子在离子液体/水溶液二元系统中的电迁移行为在很多领域受到了越来越多的关注。本文通过研究不同条件下离子液体离子在电极液中的浓度变化,系统地研究了电极溶液酸—碱度,电极溶液中电解质浓度以及离子液体中溶解LiN (CF_3SO_2)_2与否对[C_6MIm]~+离子电迁移的影响。总的来说,随着电流的增加,[C_6MIm]~+离子向阴极水溶液的迁移量随之增加,向阳极水溶液的迁移量随之减少;然而N(CF_3SO_2)~-_2离子向阳极水溶液的迁移量随之增加,向阴极水溶液的迁移量随之减少。当电极溶液为碱性,[C_6MIm]~+离子的迁移量明显减少。在电极溶液中溶入LiN (CF_3SO_2)_2时或者将LiN (CF_3SO_2)_2溶入离子液体时,[C_6MIm]~+离子的迁移量也明显受到抑制。
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/34207
Collection中国科学院青海盐湖研究所
Affiliation1.中国科学院青海盐湖研究所中国科学院盐湖资源综合高效利用重点实验室
2.青海省盐湖资源综合利用工程技术中心
3.中国科学院大学
Recommended Citation
GB/T 7714
王明勇,孙进贺,张鹏瑞,等. Electromigration of [C6MIm][TFSI]from Ionic Liquids Bulk to Aqueous Solutions[J]. 盐湖研究,2021,29(02):35-43.
APA 王明勇.,孙进贺.,张鹏瑞.,黄超驰.,张茜.,...&贾永忠.(2021).Electromigration of [C6MIm][TFSI]from Ionic Liquids Bulk to Aqueous Solutions.盐湖研究,29(02),35-43.
MLA 王明勇,et al."Electromigration of [C6MIm][TFSI]from Ionic Liquids Bulk to Aqueous Solutions".盐湖研究 29.02(2021):35-43.
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