Photocatalytic Performance and Degradation Mechanism of Aspirin by TiO2 through Response Surface Methodology

doi:10.3390/catal8030118

	Photocatalytic Performance and Degradation Mechanism of Aspirin by TiO2 through Response Surface Methodology
	Li, Lezhuo; Ma, Qiuling; Wang, Sanfan; Song, Sanxiang; Li, Bo; Guo, Ruonan; Cheng, Xiuwen; Cheng, Qingfeng
第一作者	Li, Lezhuo
	2018-03
发表期刊	CATALYSTS
ISSN	2073-4344
卷号	8 期号:3
摘要	In the present work, the photocatalytic performance of P25TiO(2) was investigated by means of the degradation of aspirin, while the reaction system was systematically optimized by central composite design (CCD) based on the response surface methodology (RSM). In addition, three variables of initial pH value, initial aspirin concentration and P25 concentration were selected to assess the dependence of degradation efficiencies of aspirin. Meanwhile, a predicted model of degradation efficiency was estimated and checked using analysis of variance (ANOVA). The results indicated that the PC removal of aspirin by P25 was significantly influenced by all these variables in descending order as follows: P25 concentration > initial aspirin concentration > initial pH value. Moreover, the parameters were optimized by the CCD method. Under the conditions of an initial pH value of 5, initial aspirin concentration of 10 mg/L and P25 concentration of 50 mg/L, the degradation efficiency of aspirin was 98.9% with 60 min of Xenon lamp irradiation. Besides, based on the liquid chromatography-mass spectrometry measurements, two main PC degradation pathways of aspirin by TiO2 were deduced and the tentative degradation mechanism was also proposed.
DOI	10.3390/catal8030118
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/34434
专题	盐湖资源综合利用工程技术中心
推荐引用方式 GB/T 7714	Li, Lezhuo,Ma, Qiuling,Wang, Sanfan,et al. Photocatalytic Performance and Degradation Mechanism of Aspirin by TiO2 through Response Surface Methodology[J]. CATALYSTS,2018,8(3).
APA	Li, Lezhuo.,Ma, Qiuling.,Wang, Sanfan.,Song, Sanxiang.,Li, Bo.,...&Cheng, Qingfeng.(2018).Photocatalytic Performance and Degradation Mechanism of Aspirin by TiO2 through Response Surface Methodology.CATALYSTS,8(3).
MLA	Li, Lezhuo,et al."Photocatalytic Performance and Degradation Mechanism of Aspirin by TiO2 through Response Surface Methodology".CATALYSTS 8.3(2018).

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