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Synthesis of Magnetic CoFe2O4 Nanoparticles and Their Efficient Degradation of Diclofenac by Activating Persulfate via Formation of Sulfate Radicals
Zhang, Huixuan; Li, Huarui; Wang, Zhongjuan; Li, Bo; Cheng, Xiuwen; Cheng, Qingfeng
第一作者Zhang, Huixuan
2018-10
发表期刊JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
ISSN1533-4880
卷号18期号:10页码:6942-6948
摘要In this study, magnetic CoFe2O4 nanoparticles were synthesized by hydrothermal method by using ferric nitrate and cobalt nitrate as raw materials. Subsequently, physicochemical properties of the resulting CoFe2O4 nanoparticles were systematically studied by scanning electron microscope, X-ray diffraction, N-2 adsorption/desorption, Fourier transformation infrared spectroscopy and Vibration sample magnetometer measurement. Results indicated that CoFe2O4 nanoparticles with cubic spinel structure possessed an average diameter of 6.9 nm, specific surface area of 103.48 m(2) . g(-1), saturation magnetization of 54.65 A . m(2) (emu . g(-1)) and coercivity of 1.76x10(4) A . m(-1). Furthermore, scavenging experiments revealed that sulfate radicals ((SO4-)-S-center dot) was the main active species derived from persulfates, in which 72.3% of diclofenac could be degraded within 30 min treatment. This study provides a promising strategy to synthesize versatile catalyst which would be potentially applied in pharmaceutical wastewater purification.
DOI10.1166/jnn.2018.15800
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/34451
专题盐湖资源综合利用工程技术中心
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Zhang, Huixuan,Li, Huarui,Wang, Zhongjuan,et al. Synthesis of Magnetic CoFe2O4 Nanoparticles and Their Efficient Degradation of Diclofenac by Activating Persulfate via Formation of Sulfate Radicals[J]. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2018,18(10):6942-6948.
APA Zhang, Huixuan,Li, Huarui,Wang, Zhongjuan,Li, Bo,Cheng, Xiuwen,&Cheng, Qingfeng.(2018).Synthesis of Magnetic CoFe2O4 Nanoparticles and Their Efficient Degradation of Diclofenac by Activating Persulfate via Formation of Sulfate Radicals.JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,18(10),6942-6948.
MLA Zhang, Huixuan,et al."Synthesis of Magnetic CoFe2O4 Nanoparticles and Their Efficient Degradation of Diclofenac by Activating Persulfate via Formation of Sulfate Radicals".JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY 18.10(2018):6942-6948.
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