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Pretreatment of Graphite Anodes with Lithium Sulfate to Improve the Cycle Performance of Lithium-Ion Batteries
Cui, Xiaoling; Tang, Fengjuan; Li, Chunlei; Zhang, Yu; Wang, Peng; Li, Shiyou; Ye, Xiushen
第一作者Cui, Xiaoling
2017-04
发表期刊ENERGY TECHNOLOGY
ISSN2194-4288
卷号5期号:4页码:549-556
摘要Graphite electrode surfaces are pretreated by spray-deposition method with 0.5 mol L-1 Li2SO4 aqueous solution. The physical and electrochemical properties of a solid electrolyte interphase (SEI) film formed on the surface of Li2SO4-treated graphite electrode are investigated by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and electrochemical measurements. The results show that the SEI film formed, promoted by Li2SO4, is thin, stable, effective, and elastic to accommodate volume changes of graphite electrode during electrochemical cycles. Due to the fact that the Li/mesophase carbon microbeads (MCMB) cell based on Li2SO4-treated graphite electrode exhibits excellent cycling performance and low interfacial impedance, we can deduce that such modifies have positive implications for lithium-ion batteries (LIBs), offering the possibility of faster-charging LIBs and LIBs that are suitable for rate-demanding applications, such electric vehicles and hybrid electric vehicles.
DOI10.1002/ente.201600360
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/34525
专题盐湖资源与化学实验室
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GB/T 7714
Cui, Xiaoling,Tang, Fengjuan,Li, Chunlei,et al. Pretreatment of Graphite Anodes with Lithium Sulfate to Improve the Cycle Performance of Lithium-Ion Batteries[J]. ENERGY TECHNOLOGY,2017,5(4):549-556.
APA Cui, Xiaoling.,Tang, Fengjuan.,Li, Chunlei.,Zhang, Yu.,Wang, Peng.,...&Ye, Xiushen.(2017).Pretreatment of Graphite Anodes with Lithium Sulfate to Improve the Cycle Performance of Lithium-Ion Batteries.ENERGY TECHNOLOGY,5(4),549-556.
MLA Cui, Xiaoling,et al."Pretreatment of Graphite Anodes with Lithium Sulfate to Improve the Cycle Performance of Lithium-Ion Batteries".ENERGY TECHNOLOGY 5.4(2017):549-556.
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