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Electrochemical deposition of magnesium from analogous ionic liquid based on dimethylformamide
Wang, Huaiyou1,2; Jia, Yongzhong1; Wang, Xiaohua1; Yao, Ying1; Yue, Duyuan1,2; Jing, Yan1
2013-10-01
Source PublicationELECTROCHIMICA ACTA
Volume108Pages:384-389
SubtypeArticle
AbstractIn this paper, a homogeneous, colorless analogous ionic liquid containing dimethylformamide (DMF) and magnesium chloride hexahydrate is synthesized. The conductivity of analogous ionic liquid is measured as a function of temperature and composition. Irreversible electrochemical behavior was generally observed by cyclic voltammetry (CV) in the analogous ionic liquid based electrolytes containing simple Mg salt. CV also shows that the reducing reaction of Mg2+ is a diffusion control process. Electrochemical impedance spectroscopy (EIS) of analogous ionic liquid was measured at 20 degrees C, 40 degrees C and 60 degrees C. Electrodeposition of magnesium metal from analogous ionic liquid has been studied. The Mg deposits are also systematically characterized by the techniques of powder X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS). Results showed that magnesium was found in the deposited film. (C) 2013 Elsevier Ltd. All rights reserved.
KeywordConductivity Cyclic Voltammetry Curve Magnesium Electrodeposition Analogous Ionic Liquid
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordDEEP EUTECTIC SOLVENT ; ELECTRODEPOSITION ; CODEPOSITION ; ALLOYS ; SALTS ; ZINC
Indexed BySCI
Language英语
WOS Research AreaElectrochemistry
WOS SubjectElectrochemistry
WOS IDWOS:000328014000050
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/4417
Collection青海盐湖研究所知识仓储
盐湖资源综合利用工程技术中心
盐湖资源与化学实验室
Affiliation1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Wang, Huaiyou,Jia, Yongzhong,Wang, Xiaohua,et al. Electrochemical deposition of magnesium from analogous ionic liquid based on dimethylformamide[J]. ELECTROCHIMICA ACTA,2013,108:384-389.
APA Wang, Huaiyou,Jia, Yongzhong,Wang, Xiaohua,Yao, Ying,Yue, Duyuan,&Jing, Yan.(2013).Electrochemical deposition of magnesium from analogous ionic liquid based on dimethylformamide.ELECTROCHIMICA ACTA,108,384-389.
MLA Wang, Huaiyou,et al."Electrochemical deposition of magnesium from analogous ionic liquid based on dimethylformamide".ELECTROCHIMICA ACTA 108(2013):384-389.
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