Knowledge Management System Of Qinghai Institute of Salt Lakes,CAS
Seven novel Sr-II-Sm-III and Sr-II-Dy-III coordination polymers: construction of five classes of structural topologies using different amounts of imidazole | |
Chen, Yanmei1; Cao, Yanyuan1; Chen, Wenqian1; Gao, Qian1; Li, Lei1; Gao, Dandan2; Liu, Wei1; Li, Yahong1,3; Li, Wu2 | |
2013 | |
发表期刊 | DALTON TRANSACTIONS |
卷号 | 42期号:27页码:10011-10018 |
摘要 | The employment of pyridine-2,6-dicarboxylic acid (H(2)pda) and imidazole (im) in the synthesis of Sr-II-Sm-III and Sr-II-Dy-III coordination polymers has been reported. Seven novel heterometallic coordination polymers of compositions, [Dy3Sr3(pda)(7)(Hpda)(H2O)(9)]center dot 6H(2)O (1), [LnSr(pda)(3)(H2O)(5)]center dot Him center dot H2O (Ln = Sm(2), Dy(3)), [Ln(2)Sr(pda)(6)(H2O)(5)]center dot 4Him center dot C2H5OH center dot nH(2)O (Ln = Sm(4), n = 4; Dy(5), n = 5), [Sm2Sr2(pda)(5)(H2O)(9)]center dot 2H(2)O (6) and [DySr(pda)(3)(H2O)(4)]center dot Him center dot 3H(2)O (7), have been prepared and characterized. Complexes 1, 2-3, and 6 display three varieties of 2-D structures. 4-5 and 7 exhibit two types of 1-D chain structures. The structures of the complexes could be controlled via choosing appropriate starting materials and tuning the amount of imidazole. The photo-luminescent properties of these complexes have been investigated. The results show the exclusive luminescence emission bands being characteristic of Sm-III and Dy-III. |
语种 | 英语 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.isl.ac.cn/handle/363002/4434 |
专题 | 青海盐湖研究所知识仓储 盐湖资源综合利用工程技术中心 |
作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Yanmei,Cao, Yanyuan,Chen, Wenqian,et al. Seven novel Sr-II-Sm-III and Sr-II-Dy-III coordination polymers: construction of five classes of structural topologies using different amounts of imidazole[J]. DALTON TRANSACTIONS,2013,42(27):10011-10018. |
APA | Chen, Yanmei.,Cao, Yanyuan.,Chen, Wenqian.,Gao, Qian.,Li, Lei.,...&Li, Wu.(2013).Seven novel Sr-II-Sm-III and Sr-II-Dy-III coordination polymers: construction of five classes of structural topologies using different amounts of imidazole.DALTON TRANSACTIONS,42(27),10011-10018. |
MLA | Chen, Yanmei,et al."Seven novel Sr-II-Sm-III and Sr-II-Dy-III coordination polymers: construction of five classes of structural topologies using different amounts of imidazole".DALTON TRANSACTIONS 42.27(2013):10011-10018. |
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