Formation of C-C and C-O bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands

ISL OpenIR > 青海盐湖研究所知识仓储

	Formation of C-C and C-O bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands
	Lei, Tao 1,2; Gao, Qian 1; Chen, Wen-Qian 1; Chen, Yan-Mei 1; Liu, Wei 1; Yang, Shu-Min 1; Chen, Wei-Wei 1; Li, Wu 2; Li, Yahong 1,3
	2013-04-01
发表期刊	INORGANIC CHEMISTRY COMMUNICATIONS
卷号	30 页码:92-96
关键词	Crystal Structures Nickel(Ii) Complexes In Situ Metal-ligand Reaction Carbon-carbon Bond Making Carbon-oxygen Bond Formation
摘要	Under solvothermal conditions, complexes Ni(HL2) (1) and Ni(L3)center dot MeOH (2 center dot MeOH) (H(3)L2=N-(2-(2-hydroxybenzylideneamino)-1-(2-hydroxyphenyl)-2-(pyridin-2-yl)ethyl)picolinamide; H(2)L3=1-(pyridin-2-yl)prop-1-ene-1,2-diyl)bis(azan-1-yl-1-ylidene)bis((methan-1-yl-1-ylidene)diphenol) have been synthesized from the reaction of Ni(CH3COO)(2)center dot 4H(2)O with 2-((pyridin-2-ylmethyleneamino)methyl)phenol (HL1) at 70 and 90 degrees C, respectively. The complexes were characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. The plausible mechanisms for the formation of H(3)L2 and H(3)L3 via solvothermal in situ metal-ligand reactions were proposed. (C) 2013 Elsevier B.V. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/4454
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, CAS Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Lei, Tao,Gao, Qian,Chen, Wen-Qian,et al. Formation of C-C and C-O bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2013,30:92-96.
APA	Lei, Tao.,Gao, Qian.,Chen, Wen-Qian.,Chen, Yan-Mei.,Liu, Wei.,...&Li, Yahong.(2013).Formation of C-C and C-O bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands.INORGANIC CHEMISTRY COMMUNICATIONS,30,92-96.
MLA	Lei, Tao,et al."Formation of C-C and C-O bonds via solvothermal in situ metal-ligand reaction: Synthesis and crystal structures of two novel nickel(II) complexes supported by in situ generated polydentate Schiff base ligands".INORGANIC CHEMISTRY COMMUNICATIONS 30(2013):92-96.