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Fabrication of Poly(triazine dithiol) Functional Nanofilm by Galvanostatic Polymerization on Aluminum
Wang, Yabin1; Bian, Shaoju; Liu, Xin; Wang, Fang; Meng, Qingfen
2013-08-01
Source PublicationINTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
Volume8Issue:8Pages:10818-10826
SubtypeArticle
AbstractThe functional polymeric nanofilm of 6-(N-allyl-1, 1, 2, 2-tetrahydroperfluorododecyl) amino-1, 3, 5-triazine-2, 4-dithiol monosodium (ATP) was prepared on aluminum surface by galvanostatic polymerization technique. The chemical structure of nanofilm was characterized by Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS). Adsorption peaks in FTIR and C1s, N1s, S2p and F1s peaks in the XPS spectra indicate that the polymeric nanofilm is successfully fabricated in NaNO2 electrolyte solution. The influencing factors were investigated by potential and eletropolymerization time curves (E-t), XPS spectra, film weight, film thickness and AFM. All the results show that the optimal electrochemical polymerization current, temperature and time are 0.4mA/cm(2), 15 degrees C and 8min respectively. Uniform and compact polymeric nanofilm of ATP could be obtained under these conditions. It is expected that this technique will be applied in preparation of lubricating, anti-tribological and hydrophobic surface on aluminum with functional triazinedithiols.
KeywordTriazinedithiol Monosodium Functional Polymeric Nanofilms Galvanostatic Polymerization Aluminum
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordELECTROCHEMICAL POLYMERIZATION ; MAGNESIUM ALLOYS ; SURFACE ; TRIAZINEDITHIOL ; CORROSION ; PLATES ; IRON ; FILM
Indexed BySCI
Language英语
WOS Research AreaElectrochemistry
WOS SubjectElectrochemistry
WOS IDWOS:000323548600053
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/4465
Collection青海盐湖研究所知识仓储
Affiliation1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China
2.Northwest Agr & Forest Univ, Coll Sci, Yangling 712100, Shaanxi, Peoples R China
Recommended Citation
GB/T 7714
Wang, Yabin,Bian, Shaoju,Liu, Xin,et al. Fabrication of Poly(triazine dithiol) Functional Nanofilm by Galvanostatic Polymerization on Aluminum[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2013,8(8):10818-10826.
APA Wang, Yabin,Bian, Shaoju,Liu, Xin,Wang, Fang,&Meng, Qingfen.(2013).Fabrication of Poly(triazine dithiol) Functional Nanofilm by Galvanostatic Polymerization on Aluminum.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,8(8),10818-10826.
MLA Wang, Yabin,et al."Fabrication of Poly(triazine dithiol) Functional Nanofilm by Galvanostatic Polymerization on Aluminum".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 8.8(2013):10818-10826.
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