Accurate and Precise Determination of Boron Isotopic Ratios at Low Concentration by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs2BO2+ Ions

ISL OpenIR > 青海盐湖研究所知识仓储

	Accurate and Precise Determination of Boron Isotopic Ratios at Low Concentration by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs2BO2+ Ions
	He, Mao-yong 1; Xiao, Ying-kai 2; Jin, Zhang-dong 1; Ma, Yun-qi 2; Xiao, Jun 1; Zhang, Yan-ling 2; Luo, Chong-guang 3; Zhang, Fei 1
	2013-07-02
发表期刊	ANALYTICAL CHEMISTRY
卷号	85 期号:13 页码:6248-6253
摘要	A static double-collector system for accurate, precise, and rapid boron isotope analysis has been established by employing a newly fixed Faraday H3 and H4 cup enabling simultaneously collected Cs2BO2+ ion beams (m/z = 308 and 309) on a Finnigan-MAT Triton thermal ionization mass spectrometer of boron (Triton B). The experimental result indicated that Cs2BO2+ ion beams (m/z = 308 and 309) were simultaneously collected using a fixed Faraday H3 and H4 cup without using the "Zoom Quad" function and reduced accelerating voltage. Furthermore, the method enabled the measurement of samples containing as little as 20 ng of boron. An analysis of the National Institute of Standards and Technology standard reference material (NIST SRM) 951 standard showed external reproducibility (2RSD) of +/- 0.013 parts per thousand, +/- 0.013 parts per thousand, and +/- 0.019 parts per thousand for 100, 50, and 20 ng of boron, respectively. The present method of static multicollection of Cs2BO2+ ions is applicable to a wide field of boron isotopic research that requires high precision and accuracy to analyze samples with low boron concentrations, including pore fluids, foraminifera, rivers, rainwater, and other natural samples.
语种	英语
引用统计	正在获取...
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/4468
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Chinese Acad Sci, Inst Earth Environm, State Key Lab Loess & Quaternary Geol, Xian 710075, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, CAS Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Chinese Acad Sci, Inst Geochem, State Key Lab Ore Deposit Geochem, Guiyang 550002, Peoples R China
推荐引用方式 GB/T 7714	He, Mao-yong,Xiao, Ying-kai,Jin, Zhang-dong,et al. Accurate and Precise Determination of Boron Isotopic Ratios at Low Concentration by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs2BO2+ Ions[J]. ANALYTICAL CHEMISTRY,2013,85(13):6248-6253.
APA	He, Mao-yong.,Xiao, Ying-kai.,Jin, Zhang-dong.,Ma, Yun-qi.,Xiao, Jun.,...&Zhang, Fei.(2013).Accurate and Precise Determination of Boron Isotopic Ratios at Low Concentration by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs2BO2+ Ions.ANALYTICAL CHEMISTRY,85(13),6248-6253.
MLA	He, Mao-yong,et al."Accurate and Precise Determination of Boron Isotopic Ratios at Low Concentration by Positive Thermal Ionization Mass Spectrometry Using Static Multicollection of Cs2BO2+ Ions".ANALYTICAL CHEMISTRY 85.13(2013):6248-6253.