A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property

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	A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property
	Zhang, Su-Yun 1; Chen, Wen-Qian 1; Hu, Bin 2; Chen, Yan-Mei 1; Li, Wu 2; Li, Yahong 1,3
	2012-02-01
发表期刊	INORGANIC CHEMISTRY COMMUNICATIONS
卷号	16 页码:74-77
关键词	Tetranuclear Cubane-like Nickel Complex Magnetic Properties
摘要	The tetranuclear cubane-like complex of the formula [Ni-4(HL1)(3)(HL2)(H2O)(CH3OH)] [CH3COO]center dot 2CH(3)OH center dot CH3CN (1) (H(3)L1=3-(2-hydroxybenzylideneamino)propane-1,2-diol; H(2)L2=3-aminoprppane-1,2-diol) has been prepared by a one-pot reaction of nickel(II) acetate, salicylaldehyde and 3-aminopropane-1,2-diol, where the H(3)L1 ligand was generated in situ via the condensation reaction between salicylaldehyde and 3-aminopropane-1,2-diol. The X-ray diffraction analysis of the complex showed a Ni4O4 cubane arrangement and the coordination environments of four Ni(II) ions are different from each other. Magnetic studies indicated ferromagnetic behavior for the complex. The magnetic data were fitted and the parameters were given as g=2.43, J(1)=15.96, and J(2)=4.116. (C) 2011 Elsevier B.V. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5576
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, CAS Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Su-Yun,Chen, Wen-Qian,Hu, Bin,et al. A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2012,16:74-77.
APA	Zhang, Su-Yun,Chen, Wen-Qian,Hu, Bin,Chen, Yan-Mei,Li, Wu,&Li, Yahong.(2012).A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property.INORGANIC CHEMISTRY COMMUNICATIONS,16,74-77.
MLA	Zhang, Su-Yun,et al."A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property".INORGANIC CHEMISTRY COMMUNICATIONS 16(2012):74-77.