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A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property
Zhang, Su-Yun1; Chen, Wen-Qian1; Hu, Bin2; Chen, Yan-Mei1; Li, Wu2; Li, Yahong1,3
2012-02-01
发表期刊INORGANIC CHEMISTRY COMMUNICATIONS
卷号16页码:74-77
关键词Tetranuclear Cubane-like Nickel Complex Magnetic Properties
摘要The tetranuclear cubane-like complex of the formula [Ni-4(HL1)(3)(HL2)(H2O)(CH3OH)] [CH3COO]center dot 2CH(3)OH center dot CH3CN (1) (H(3)L1=3-(2-hydroxybenzylideneamino)propane-1,2-diol; H(2)L2=3-aminoprppane-1,2-diol) has been prepared by a one-pot reaction of nickel(II) acetate, salicylaldehyde and 3-aminopropane-1,2-diol, where the H(3)L1 ligand was generated in situ via the condensation reaction between salicylaldehyde and 3-aminopropane-1,2-diol. The X-ray diffraction analysis of the complex showed a Ni4O4 cubane arrangement and the coordination environments of four Ni(II) ions are different from each other. Magnetic studies indicated ferromagnetic behavior for the complex. The magnetic data were fitted and the parameters were given as g=2.43, J(1)=15.96, and J(2)=4.116. (C) 2011 Elsevier B.V. All rights reserved.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5576
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, CAS Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
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Zhang, Su-Yun,Chen, Wen-Qian,Hu, Bin,et al. A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2012,16:74-77.
APA Zhang, Su-Yun,Chen, Wen-Qian,Hu, Bin,Chen, Yan-Mei,Li, Wu,&Li, Yahong.(2012).A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property.INORGANIC CHEMISTRY COMMUNICATIONS,16,74-77.
MLA Zhang, Su-Yun,et al."A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: Synthesis, crystal structure and magnetic property".INORGANIC CHEMISTRY COMMUNICATIONS 16(2012):74-77.
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