Co(II) and Ni(II) complexes incorporating N-acetimidoylacetamidine ligand: Synthesis and structures

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	Co(II) and Ni(II) complexes incorporating N-acetimidoylacetamidine ligand: Synthesis and structures
	Chen, Yanmei 1,2; Hu, Bin 1; Xu, Bin 1; Zhang, Suyun 2; Zhou, Fengying 2; Li, Yahong 1,2
	2012-03-01
发表期刊	RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
卷号	57 期号:3 页码:386-389
摘要	Two new square planar complexes with the formula Co(L)(2) center dot CH3OH (1) and Ni(L)(2) center dot CH3OH (2) (HL = HN{C(Me)=NH}(2) = N-acetimidoylacetamidine) have been synthesized by solvothermal reactions in methanol/acetonitrile. N-acetimidoylacetamidine ligand was derived from the self-condensation reaction of acetonitrile, and the reaction was promoted by the cooperation of M(II) (M = Co in 1 and M = Ni in 2) with diphenylcarbazide. 1 and 2 are characterized by single crystal X-ray diffraction, elemental analysis and infrared spectrum. Both complexes crystallize in the monoclinic space group P2(1)/c with a = 9.329(6) , b = 11.494(7) , c = 13.040(8) , beta = 92.945(11)A degrees, V = 1396.3(16) (3) and Z = 4 for 1, and a = 9.323(4), b = 11.512(5) , c = 13.020(6), beta = 92.819(7)A degrees, V = 1395.7(10)(3) and Z = 4 for 2.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5587
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 2.Suzhou Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem & Chem Engn, Suzhou 215123, Peoples R China
推荐引用方式 GB/T 7714	Chen, Yanmei,Hu, Bin,Xu, Bin,et al. Co(II) and Ni(II) complexes incorporating N-acetimidoylacetamidine ligand: Synthesis and structures[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2012,57(3):386-389.
APA	Chen, Yanmei,Hu, Bin,Xu, Bin,Zhang, Suyun,Zhou, Fengying,&Li, Yahong.(2012).Co(II) and Ni(II) complexes incorporating N-acetimidoylacetamidine ligand: Synthesis and structures.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,57(3),386-389.
MLA	Chen, Yanmei,et al."Co(II) and Ni(II) complexes incorporating N-acetimidoylacetamidine ligand: Synthesis and structures".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 57.3(2012):386-389.