A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures

ISL OpenIR > 青海盐湖研究所知识仓储

	A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures
	Zhang, Suyun 1; Chen, Wenqian 1; Hu, Bin2 ; Chen, Yanmei 1; Zheng, Lina 1; Li, Yahong 1,3; Li, Wu 2
	2012
发表期刊	JOURNAL OF COORDINATION CHEMISTRY
卷号	65 期号:23 页码:4147-4155
关键词	Tetranuclear Cubane-like Nickel Copper
摘要	A tetranuclear cubane-like cluster [Ni-4(HL)(4)(DMSO)(2)] center dot 2DMSO center dot H2O (1) and a dinuclear compound [Cu2Cl2(H2L)(2)] center dot 1.5MeOH (2) (H3L = 3-(2-hydroxy-benzylideneamino)propane-1,2-diol) have been prepared and characterized by X-ray single crystal diffraction, IR, and elemental analysis. The X-ray diffraction analysis indicated that the four metals of 1 showed a Ni4O4 cubane arrangement, and two of the six faces of the Ni4O4 cubane were capped by DMSO. Complex 1 is the first reported DMSO capped Ni4O4 cubane cluster. Complex 2 contains a u(2)-Cl bridged dinuclear core with each Cu-II ion exhibiting pseudo square pyramidal geometry.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5643
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所盐湖资源与化学实验室
作者单位	1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 73000, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Suyun,Chen, Wenqian,Hu, Bin,et al. A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures[J]. JOURNAL OF COORDINATION CHEMISTRY,2012,65(23):4147-4155.
APA	Zhang, Suyun.,Chen, Wenqian.,Hu, Bin.,Chen, Yanmei.,Zheng, Lina.,...&Li, Wu.(2012).A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures.JOURNAL OF COORDINATION CHEMISTRY,65(23),4147-4155.
MLA	Zhang, Suyun,et al."A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear copper complex incorporating a hydroxyl-rich ligand: syntheses and crystal structures".JOURNAL OF COORDINATION CHEMISTRY 65.23(2012):4147-4155.