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Copper(II) and Cadmium(II) Complexes Based on N,N-Bis(3, 5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine Ligand: Syntheses, Structures, Magnetic, and Luminescent Properties
Yang, Lijuan1; Chen, Wenqian1; Chen, Yanmei1; Liu, Wei1; Lei, Tao2; Li, Lei1; Lin, Miaoshui1; Wu, Jian1; Cao, Yanyuan1; Li, Wu2; Li, Yahong1,3
2012-09-01
Source PublicationZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume638Issue:11Pages:1833-1838
SubtypeArticle
AbstractThe reaction of the aryl-oxide ligand H2L [H2L = N,N-bis(3, 5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine] with CuSO4 center dot 5H2O, CuCl2 center dot 2H2O, CuBr2, CdCl2 center dot 2.5H2O, and Cd(OAc)2 center dot 2H2O, respectively, under hydrothermal conditions gave the complexes [Cu(H2L1)2]center dot SO4 center dot 3CH3OH (1), [Cu2(H2L2)2Cl4] (2), [Cu2(H2L2)2Br4] (3), [Cd2(HL)2Cl2] (4), and [Cd2(L)2(CH3COOH)2]center dot H2L (5), where H2L1 [H2L1 = 2, 4-dimethyl-6-((pyridin-2-ylmethylamino)methyl)phenol] and H2L2 [H2L2 = 2-(2, 4-dimethyl-6-((pyridin-2-ylmethylamino)methyl)phenoxy)-4, 6-dimethylphenol] were derived from the solvothermal in situ metal/ligand reactions. These complexes were characterized by IR spectroscopy, elementary analysis, and X-ray diffraction. A low-temperature magnetic susceptibility measurement for the solid sample of 2 revealed antiferromagnetic interactions between two central copper(II) atoms. The emission property studies for complexes 4 and 5 indicated strong luminescence emission.
KeywordAryl-oxide Ligand In Situ Metal Ligand Reaction Coordination Complexes Luminescence Magnetic Properties
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordCU-II ; ZIRCONIUM COMPLEXES ; DIAMINE-BIS(PHENOLATE) LIGANDS ; COORDINATION CHEMISTRY ; DONOR LIGANDS ; POLYMERIZATION ; CD(II) ; ZN(II) ; AMINE ; CATALYSIS
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000308991600029
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5652
Collection青海盐湖研究所知识仓储
Affiliation1.Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Yang, Lijuan,Chen, Wenqian,Chen, Yanmei,et al. Copper(II) and Cadmium(II) Complexes Based on N,N-Bis(3, 5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine Ligand: Syntheses, Structures, Magnetic, and Luminescent Properties[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2012,638(11):1833-1838.
APA Yang, Lijuan.,Chen, Wenqian.,Chen, Yanmei.,Liu, Wei.,Lei, Tao.,...&Li, Yahong.(2012).Copper(II) and Cadmium(II) Complexes Based on N,N-Bis(3, 5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine Ligand: Syntheses, Structures, Magnetic, and Luminescent Properties.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,638(11),1833-1838.
MLA Yang, Lijuan,et al."Copper(II) and Cadmium(II) Complexes Based on N,N-Bis(3, 5-dimethyl-2-hydroxybenzyl)-N-(2-pyridylmethyl)amine Ligand: Syntheses, Structures, Magnetic, and Luminescent Properties".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 638.11(2012):1833-1838.
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