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Investigations of BaxSr1-xTiO3 ceramics and powders prepared by direct current arc discharge technique
Li, Shuangbin1,2; Yao, Ying1; Yuzyuk, Yu. I.3; Jia, Yongzhong1; Wang, Xiaohan1,2; Xie, Shaolei1; Jing, Yan1
2014-09-01
发表期刊APPLIED PHYSICS LETTERS
卷号105期号:9
摘要BaxSr1-xTiO3 ceramics with x ranging from 0 to 1 were prepared by direct current arc discharge technique and studied by means of x-ray diffraction (XRD) and Raman spectroscopy. The cubic-tetragonal ferroelectric phase transition in BaxSr1-xTiO3 ceramics was found to occur at x approximate to 0.75. XRD investigation of as-grown BaTiO3 ceramics revealed co-existence of tetragonal and hexagonal modifications with a small amount of impurity phase BaTi4O9. No evidences of hexagonal phase were observed in Raman spectra of as-grown BaTiO3 ceramics, while Raman peaks related to hexagonal phase were clearly observed in the spectrum of fine-grain powders prepared from the same ceramics. A core-shell model for BaTiO3 ceramics prepared by direct current arc discharge technique is proposed. Absence of the hexagonal phase in any BaxSr1-xTiO3 solid solution with x<1 is discussed in the frame of specific atomic arrangement. (C) 2014 AIP Publishing LLC.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5669
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
盐湖资源综合利用工程技术中心
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Southern Fed Univ, Fac Phys, Rostov Na Donu 344090, Russia
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Li, Shuangbin,Yao, Ying,Yuzyuk, Yu. I.,et al. Investigations of BaxSr1-xTiO3 ceramics and powders prepared by direct current arc discharge technique[J]. APPLIED PHYSICS LETTERS,2014,105(9).
APA Li, Shuangbin.,Yao, Ying.,Yuzyuk, Yu. I..,Jia, Yongzhong.,Wang, Xiaohan.,...&Jing, Yan.(2014).Investigations of BaxSr1-xTiO3 ceramics and powders prepared by direct current arc discharge technique.APPLIED PHYSICS LETTERS,105(9).
MLA Li, Shuangbin,et al."Investigations of BaxSr1-xTiO3 ceramics and powders prepared by direct current arc discharge technique".APPLIED PHYSICS LETTERS 105.9(2014).
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