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Five heterometallic Sr-II-M-II (M = Co, Ni, Zn, Cu) 3-D coordination polymers: Synthesis, structures and magnetic properties
Chen, Yanmei1,2; Gao, Qian1; Zhang, Haifeng1; Gao, Dandan2; Li, Yahong1,3; Liu, Wei1; Li, Wu2
2014-03-20
发表期刊POLYHEDRON
卷号71页码:91-98
关键词Heterometallic Complexes Pyridine-2 Alkaline Earth Metal 3-dicarboxylic Acid Magnetic Properties
摘要Five heterometallic coordination polymers based on pyridine 2,3-dicarboxylic acid (H(2)pydc), namely [MSr(pydc)(2)(H2O)(n) (M = Co (1), Ni (2)), [MSr2(pydc)(3)(H2O)(4)](n)center dot 2nH(2)O (M = Ni (3), Zn (4)) and [CuSr(pydc)(2)(H2O)(3)](n)center dot 2nH(2)O (5), have been synthesized via rationally choosing the appropriate metal salts and dexterously adjusting the pH values of the reaction system. X-ray crystallographic analyses reveal that the polymers display three varieties of 3-D framework structures. The magnetic properties of complexes 1 and 2 were investigated, and antiferromagnetic M-II center dot center dot center dot M-II interactions were found for both complexes. (C) 2014 Elsevier Ltd. All rights reserved.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5686
专题青海盐湖研究所知识仓储
盐湖资源综合利用工程技术中心
作者单位1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
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Chen, Yanmei,Gao, Qian,Zhang, Haifeng,et al. Five heterometallic Sr-II-M-II (M = Co, Ni, Zn, Cu) 3-D coordination polymers: Synthesis, structures and magnetic properties[J]. POLYHEDRON,2014,71:91-98.
APA Chen, Yanmei.,Gao, Qian.,Zhang, Haifeng.,Gao, Dandan.,Li, Yahong.,...&Li, Wu.(2014).Five heterometallic Sr-II-M-II (M = Co, Ni, Zn, Cu) 3-D coordination polymers: Synthesis, structures and magnetic properties.POLYHEDRON,71,91-98.
MLA Chen, Yanmei,et al."Five heterometallic Sr-II-M-II (M = Co, Ni, Zn, Cu) 3-D coordination polymers: Synthesis, structures and magnetic properties".POLYHEDRON 71(2014):91-98.
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