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Separation of Chlorine and Its Isotopic Composition in Plants
Xu Qing-Cai1; Liu Li-Hua1; Zhang Yan-Ling2
2014-08-01
发表期刊CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
卷号42期号:8页码:1094-1098
关键词Chlorine Isotope Thermal Ionization Mass Spectrometry Plant Tissue
摘要A method using dry ashing combined with triple. phase ion. exchange chromatography was developed to enrich chlorine in the plant, which could eliminate the effect of organic impurities on the determination of chlorine isotope by thermal ionization mass spectrometry. In the procedure, the recoveries indicated that there was no loss of chlorine and no fractionation of chlorine isotopes occur. The results showed that the composition of chlorine isotope in the tissues of plants in Qinghai-Tibet Plateau area and Shandong area ranged from -1.79 parts per thousand to +4.77 parts per thousand with an average of 1.20 parts per thousand. delta Cl-37 values of the two plant samples in Shandong area not more than 0 parts per thousand indicated that Cl-35 was enriched in the organs of the two plants and. delta Cl-37 values in Qinghai-Tibet Plateau area more than 0 parts per thousand indicated the deficiency of Cl-35. Chlorine isotope composition fractionated significantly in the plant samples or in different tissues of a plant. This may be caused by the differences of the medium where the plants grow, the transport of chlorine or the physiological effect in the uptake of chlorine by plants, which put forward a new insight for the further investigation of chlorine behavior in plant and the global cycling of chlorine in the biogeochemistry.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5701
专题青海盐湖研究所知识仓储
作者单位1.Linyi Univ, Shandong Prov Key Lab Water & Soil Conservat & En, Coll Chem & Chem Engn, Linyi 276005, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
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Xu Qing-Cai,Liu Li-Hua,Zhang Yan-Ling. Separation of Chlorine and Its Isotopic Composition in Plants[J]. CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,2014,42(8):1094-1098.
APA Xu Qing-Cai,Liu Li-Hua,&Zhang Yan-Ling.(2014).Separation of Chlorine and Its Isotopic Composition in Plants.CHINESE JOURNAL OF ANALYTICAL CHEMISTRY,42(8),1094-1098.
MLA Xu Qing-Cai,et al."Separation of Chlorine and Its Isotopic Composition in Plants".CHINESE JOURNAL OF ANALYTICAL CHEMISTRY 42.8(2014):1094-1098.
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