Separation and analysis of chlorine isotopes in higher plants

ISL OpenIR > 青海盐湖研究所知识仓储

	Separation and analysis of chlorine isotopes in higher plants
	Sun, Aide 1; Xu, Qingcai 1; Xu, Shujian 1; Shen, Hongyuan 1; Sun, Jing 2; Zhang, Yanling 3
	2014-08-14
发表期刊	CHEMICAL GEOLOGY
卷号	381 页码:21-25
关键词	Chlorine Isotope Fractionation Higher Plants Positive Thermal Ionization Mass Spectrometry Tissue
摘要	A novel chemical mass spectrographic method was used in the determination of chlorine (Cl) isotopes in plant tissues. The procedure includes dry ashing, three-step ion chromatographic separation of Cl isotopes, and isotope ratio determination based on Cs2Cl+ ion in positive thermal ionization mass spectrometry. The recovery of the method and the fractionation of Cl isotopes were validated using certified reference standard materials. The pretreatment strongly eliminated the effects of organic impurities and other anionic interferences, especially soluble nitrates and sulfates. The results show that there was severe fractionation of Cl isotopic composition in the tissues of plant samples, which might be caused by different molecular mechanisms of uptake and translocation of Cl within plants. The observed Cl isotopic variation is considered to be a useful isotope signature of living systems, which may be used to understand better the Cl cycling process in the environment. (C) 2014 Elsevier B.V. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5710
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Linyi Univ, Coll Resource & Environm, Shandong Prov Key Lab Water & Soil Conservat & En, Linyi 276005, Peoples R China 2.Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Key Lab Qinghai Tibet Plateau Biol Resour, Xining 810008, Peoples R China 3.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
推荐引用方式 GB/T 7714	Sun, Aide,Xu, Qingcai,Xu, Shujian,et al. Separation and analysis of chlorine isotopes in higher plants[J]. CHEMICAL GEOLOGY,2014,381:21-25.
APA	Sun, Aide,Xu, Qingcai,Xu, Shujian,Shen, Hongyuan,Sun, Jing,&Zhang, Yanling.(2014).Separation and analysis of chlorine isotopes in higher plants.CHEMICAL GEOLOGY,381,21-25.
MLA	Sun, Aide,et al."Separation and analysis of chlorine isotopes in higher plants".CHEMICAL GEOLOGY 381(2014):21-25.