Structure of aqueous potassium metaborate solution

ISL OpenIR > 青海盐湖研究所知识仓储

	Structure of aqueous potassium metaborate solution
	Zhu, F. Y.1 ; Fang, C. H.1 ; Fang, Y.1 ; Zhou, Y. Q.1 ; Ge, H. W.1 ; Liu, H. Y.1,2
	2014-07-24
发表期刊	JOURNAL OF MOLECULAR STRUCTURE
卷号	1070 页码:80-85
关键词	Potassium Metaborate Solution Structure X-ray Scattering Raman Spectra
摘要	The structure of aqueous potassium metaborate solutions has been confirmed by X-ray scattering, Raman spectra and species distribution calculation. The optimized structure of B(OH)(4)(-) was obtained by density functional theory calculation. The hydration distance and hydration number of K+ in aqueous potassium metaborate solution were given by X-ray scattering. The B-O(H2O) distance in hydrated anion B(OH)(4)(-) were determined to be 0.37 nm with the hydration number of 2.3 per hydroxyl(-OH). The K-B distance of the contact ions KB(OH)(4)(0) was measured to be 0.34 nm. (C) 2014 Elsevier B.V. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5734
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所盐湖资源与化学实验室
作者单位	1.Chinese Acad Sci, Inst Salt Lakes, Key Lab Salt Resources & Chem, Xining 8100084, Qinghai, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhu, F. Y.,Fang, C. H.,Fang, Y.,et al. Structure of aqueous potassium metaborate solution[J]. JOURNAL OF MOLECULAR STRUCTURE,2014,1070:80-85.
APA	Zhu, F. Y.,Fang, C. H.,Fang, Y.,Zhou, Y. Q.,Ge, H. W.,&Liu, H. Y..(2014).Structure of aqueous potassium metaborate solution.JOURNAL OF MOLECULAR STRUCTURE,1070,80-85.
MLA	Zhu, F. Y.,et al."Structure of aqueous potassium metaborate solution".JOURNAL OF MOLECULAR STRUCTURE 1070(2014):80-85.