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Thermodynamic modeling and experimental verification of eutectic point in the LiNO3-KNO3-Ca(NO3)(2) ternary system
Wang, Juntao1,2; Lai, Mengze1; Han, Haijun1,3; Ding, Zhiying1; Liu, Shijun1; Zeng, Dewen1,3
2015-02-01
Source PublicationJOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume119Issue:2Pages:1259-1266
SubtypeArticle
AbstractFor closing the gaps of the eutectic composition and temperature of the system LiNO3-KNO3-Ca(NO3)(2) reported by various literatures, we chose an asymmetric Toop model to simulate and predict the phase diagram of the titled system, followed by differential scanning calorimeter and thermogravimetry experiments. The eutectic composition and temperatures reported in literatures are evaluated based on the results determined in this work. It was found that the eutectic composition and temperature reported by Lehrman et al. (J Am Chem Soc 59(1):179-181, 1937) is more reliable than reported by other literatures. It is indicted that wider working temperature window (lower condensation point) in concentrated solar power plant can be obtained when the thermal medium of the titled system is prepared with the eutectic composition determined in this work.
KeywordPhase Diagram Toop Model Lino3 Kno3 Ca(No3)(2) Molten Salt
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordTHERMAL-ENERGY STORAGE ; SOLAR AIR HEATER ; PHASE-DIAGRAMS ; MOLTEN-SALT ; PERFORMANCE ; STABILITY ; POWER
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Analytical ; Chemistry, Physical
WOS IDWOS:000348192400057
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5739
Collection青海盐湖研究所知识仓储
Affiliation1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
2.Hubei Univ Sci & Technol, Sch Nucl Technol Chem & Biol, Xianning 437100, Peoples R China
3.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
Recommended Citation
GB/T 7714
Wang, Juntao,Lai, Mengze,Han, Haijun,et al. Thermodynamic modeling and experimental verification of eutectic point in the LiNO3-KNO3-Ca(NO3)(2) ternary system[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2015,119(2):1259-1266.
APA Wang, Juntao,Lai, Mengze,Han, Haijun,Ding, Zhiying,Liu, Shijun,&Zeng, Dewen.(2015).Thermodynamic modeling and experimental verification of eutectic point in the LiNO3-KNO3-Ca(NO3)(2) ternary system.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,119(2),1259-1266.
MLA Wang, Juntao,et al."Thermodynamic modeling and experimental verification of eutectic point in the LiNO3-KNO3-Ca(NO3)(2) ternary system".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 119.2(2015):1259-1266.
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