Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3

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	Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3
	Guan, W ; Yang, HZ ; Li, L ; Wang, H ; Zhang, QG
	2006-01-31
发表期刊	FLUID PHASE EQUILIBRIA
卷号	239 期号:2 页码:161-165
关键词	Isoperibol Calorimeter Solution Enthalpy Pitzer's Theory Reaction Enthalpy Ionic Liquid Bmiincl4
摘要	The ionic liquid BMIInCl4 was prepared by mixing 1-methyl-3-butylimidazolium chloride (BMIC) with InCl3. The molar solution enthalpies of BMIC and BMIInCl4 at various molalities were determined by the solution reaction isoperibol calorimeter in water at 298.15 K. In terms of Pitzer's electrolyte solution theory, the molar solution enthalpy of BMIC and BMIInCl4 at infinite dilution, Delta(s)H(m)degrees and the parameters: beta(MX)((0)L), beta(MX)((1)L) and C-MX(phi L) were obtained. Then the values of apparent relative molar enthalpy OL and relative partial molar enthalpies of solute (BMIC and BMIInCl4), L-2, were calculated, respectively. In terms of values of Delta(s)H(m)degrees of BMIC, BMIInCl4 and InCl3, the enthalpy change for the reaction: BMIC + InCl3 -> BMIInCl4 was obtained. (c) 2005 Elsevier B.V. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5770
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Liaoning Univ, Coll Environm Sci, Shenyang 110036, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Guan, W,Yang, HZ,Li, L,et al. Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3[J]. FLUID PHASE EQUILIBRIA,2006,239(2):161-165.
APA	Guan, W,Yang, HZ,Li, L,Wang, H,&Zhang, QG.(2006).Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3.FLUID PHASE EQUILIBRIA,239(2),161-165.
MLA	Guan, W,et al."Thermo-chemical properties of aqueous solution containing ionic liquids 1. The heat of reaction mixed 1-methyl-3-butylimidazolium chloride with InCl3".FLUID PHASE EQUILIBRIA 239.2(2006):161-165.