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FTIR spectroscopy of magnesium tetraborate solution
Jia, YZ; Gao, SY; Jing, Y; Zhou, YA; Xia, SP
2001
发表期刊CHEMICAL PAPERS-CHEMICKE ZVESTI
卷号55期号:3页码:162-166
文章类型Article
摘要Supersaturated aqueous solution of magnesium tetraborate (MgB4O7 . 9H(2)O), its acidified solutions with azeotropic hydrochloric acid, and its diluted solutions with water have been recorded by differential FTIR spectra. The differential FTIR spectra of borate in solutions are obtained by subtracting FTIR spectrum of water from that of the magnesium borate aqueous solutions. The results showed that various polyborate anions exist in the solutions. The bands of symmetric vibration of the corresponding polyborate anions were indicated and some assignments were tentatively given. Boron concentration and pH of solution are effective on the formations of polyborate anions. The transformations B5O6(OH)(4)(-) + OH- + H2O double left right arrow B4O5(OH)(4)(2-) + B(OH)(3) and B(OH)(3) + OH- double left right arrow B(OH)(4)(-) are main reactions in these solutions.
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]IR ; BORATE
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000170735400007
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/6053
专题青海盐湖研究所知识仓储
作者单位Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
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GB/T 7714
Jia, YZ,Gao, SY,Jing, Y,et al. FTIR spectroscopy of magnesium tetraborate solution[J]. CHEMICAL PAPERS-CHEMICKE ZVESTI,2001,55(3):162-166.
APA Jia, YZ,Gao, SY,Jing, Y,Zhou, YA,&Xia, SP.(2001).FTIR spectroscopy of magnesium tetraborate solution.CHEMICAL PAPERS-CHEMICKE ZVESTI,55(3),162-166.
MLA Jia, YZ,et al."FTIR spectroscopy of magnesium tetraborate solution".CHEMICAL PAPERS-CHEMICKE ZVESTI 55.3(2001):162-166.
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