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Phase diagram of the thermodynamically nonequilibrium state for the MgO-B2O3-18%MgCl2-H2O system at 0 degrees C
Zhu, LX; Gao, SY; Xia, SP
2002-11-01
Source PublicationRUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume47Issue:11Pages:1750-1757
SubtypeArticle
AbstractThe supersaturated solutions of MgO-B2O3-18%MgCl2-H2O with different mole ratios MgO : B2O3 were prepared and kept at 0 +/- 0.1 degreesC. The crystallization paths of boric acid, Mg-borates and Mg-oxychloride from the solutions have been determined by chemical analysis of the solution samples taken at a given time interval during crystallization, then the liquid-solid phase diagram of the thermodynamically nonequilibrium state for the MgO-B2O3-18%MgCl2-H2O system at 0degreesC has been constructed. In this phase diagram, there appears five crystallization fields, boric acid (H3BO3), mcallisterite (MgO . 3B(2)O(3) . 7.5H(2)O), hungtsaite (MgO . 2B(2)O(3) . 9H(2)O), inderite (2MgO . 3B(2)O(3) . 15H(2)O), and magnesium oxychloride (5Mg(OH)(2) . MgCl2 . 8H(2)O).
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordSALT LAKE BRINE ; CHEMISTRY ; BORATE
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000179602800028
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6068
Collection青海盐湖研究所知识仓储
AffiliationAcad Sinica, Xian Branch, Inst Salt Lakes, Xian 710043, Peoples R China
Recommended Citation
GB/T 7714
Zhu, LX,Gao, SY,Xia, SP. Phase diagram of the thermodynamically nonequilibrium state for the MgO-B2O3-18%MgCl2-H2O system at 0 degrees C[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2002,47(11):1750-1757.
APA Zhu, LX,Gao, SY,&Xia, SP.(2002).Phase diagram of the thermodynamically nonequilibrium state for the MgO-B2O3-18%MgCl2-H2O system at 0 degrees C.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,47(11),1750-1757.
MLA Zhu, LX,et al."Phase diagram of the thermodynamically nonequilibrium state for the MgO-B2O3-18%MgCl2-H2O system at 0 degrees C".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 47.11(2002):1750-1757.
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