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Li~+;Mg~(2+)/Cl~-;SO_4~(2-)-H_2O 四元体系(25℃)的介稳平衡
郭智忠; 刘子琴; 陈敬清
Source Publication化学学报
Abstract本文用等温蒸发的方法,研究了 Li~+,Mg~(2+)∥Cl~-,SO_4~(3-)-H_2O 体系(25℃)介稳相平衡,绘制了介稳相图,测定了密度、粘度、折光率、电导率和某些液相点的蒸汽压.该介稳相图由六个结晶区构成,即 LiCl·H_2O、LiCl·MgCl_2·7H_2O、MgCl_2·6H_2O、Li_2SO_4·H_2O、MgSO_4·7H_2O 和 MgSO_4·6H_2O相区.该体系的25℃介稳相图和稳定相图的差异是,新结晶区 MgSO_4·6H_2O 的出现,使 Li_2SO_4·H_2O 相区扩大,其它相区缩小.根据 Pitzer 电解质溶液理论,用单纯形法在 M68000计...
Keyword四元体系:4902 介稳相图:4713 稳定平衡相图:3235 电导率:2885 四元交互体系:2751 等温蒸发:2547 折光率:2456 溶解度数据:2377 稳定相:2166 相区:2122
Document Type期刊论文
Recommended Citation
GB/T 7714
郭智忠,刘子琴,陈敬清. Li~+;Mg~(2+)/Cl~-;SO_4~(2-)-H_2O 四元体系(25℃)的介稳平衡[J]. 化学学报,1991(10):937-943.
APA 郭智忠,刘子琴,&陈敬清.(1991).Li~+;Mg~(2+)/Cl~-;SO_4~(2-)-H_2O 四元体系(25℃)的介稳平衡.化学学报(10),937-943.
MLA 郭智忠,et al."Li~+;Mg~(2+)/Cl~-;SO_4~(2-)-H_2O 四元体系(25℃)的介稳平衡".化学学报 .10(1991):937-943.
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