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Experimental Design in the Analysis of Interferential Effects for theDetermination of Rubidium in Chloride-type Brine by Atomic AbsorptionSpectrometry Technique
Gao Dandan; Dong Yaping; Li Wu; Xu Bin; Li Yahong
2011
发表期刊CHINESE JOURNAL OF CHEMISTRY
卷号29期号:9页码:1927-1932
摘要Experimental design (DOE) was employed to precisely determine the content of rubidium in chloride type brine of Qionglai (A city in Sichuan province, southwest of China) using atomic absorption spectrometry (AAS) technique. From the statistical analysis of six factors, it was found that K(+) and Cl(-) were the significant interfering elements for the determination of rubidium. A model was established to eliminate the interference effects of K(+) and Cl(-). The experimental results indicate that, under the optimal conditions, the developed method for the rubidium determination possesses the advantages of low detection limit (0.019 mu g center dot mL(-1) at a significant level of 0.05) and higher recovery (97.2%-103.4%). Experimental design (DOE) was employed to precisely determine the content of rubidium in chloride type brine of Qionglai (A city in Sichuan province, southwest of China) using atomic absorption spectrometry (AAS) technique. From the statistical analysis of six factors, it was found that K(+) and Cl(-) were the significant interfering elements for the determination of rubidium. A model was established to eliminate the interference effects of K(+) and Cl(-). The experimental results indicate that, under the optimal conditions, the developed method for the rubidium determination possesses the advantages of low detection limit (0.019 mu g center dot mL(-1) at a significant level of 0.05) and higher recovery (97.2%-103.4%).
关键词Experimental Design Rubidium Determination Atomic Absorption
收录类别SCI
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/1866
专题青海盐湖研究所知识仓储
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Gao Dandan,Dong Yaping,Li Wu,et al. Experimental Design in the Analysis of Interferential Effects for theDetermination of Rubidium in Chloride-type Brine by Atomic AbsorptionSpectrometry Technique[J]. CHINESE JOURNAL OF CHEMISTRY,2011,29(9):1927-1932.
APA Gao Dandan,Dong Yaping,Li Wu,Xu Bin,&Li Yahong.(2011).Experimental Design in the Analysis of Interferential Effects for theDetermination of Rubidium in Chloride-type Brine by Atomic AbsorptionSpectrometry Technique.CHINESE JOURNAL OF CHEMISTRY,29(9),1927-1932.
MLA Gao Dandan,et al."Experimental Design in the Analysis of Interferential Effects for theDetermination of Rubidium in Chloride-type Brine by Atomic AbsorptionSpectrometry Technique".CHINESE JOURNAL OF CHEMISTRY 29.9(2011):1927-1932.
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