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Solubility of the Ternary System LiCl + NH4Cl + H2O
Ouyang, Haitang1; Zeng, Dewen1,2; Zhou, Hongyan1; Han, Haijun1; Yao, Yan1
2011-04-01
发表期刊JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷号56期号:4页码:1096-1104
文章类型Article
摘要Solubility isotherms of the ternary system (LiCl + NH4Cl + H2O) were elaborately determined at T = (273.15, 298.15, and 323.15) K by an isothermal method. In the equilibrium phase diagram, there are two solubility branches at 273.15 K, corresponding to the solid phase LiCl center dot 2H(2)O and NH4Cl. The invariant point composition at 273.15 K is w = 0.401 for LiCl, w = 0.024 for NH4Cl, and w = 0.575 for H2O. However, there are three solubility branches at (298.15 and 323.15) K, corresponding to the solid phase LiCl center dot H2O, NH4Cl, and a new found solid solution phase (NH4Cl)(x)(LiCl center dot H2O)(1-x). A Pitzer-Simonson-Clegg thermodynamic model was selected to represent the thermodynamic properties of this system. Thermodynamic consistence between our solubility data and water activity from other research groups shows that these concerned experimental data are reliable.
WOS标题词Science & Technology ; Physical Sciences ; Technology
关键词[WOS]ACTIVITY-COEFFICIENTS ; WATER ACTIVITIES ; IONIC-SOLUTIONS ; THERMODYNAMICS ; MULTICOMPONENT ; ELECTROLYTES ; 25-DEGREES-C ; EQUATIONS ; CHLORIDE
收录类别SCI
语种英语
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号WOS:000289403300051
引用统计
被引频次:12[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/1876
专题青海盐湖研究所知识仓储
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810007, Peoples R China
2.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
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Ouyang, Haitang,Zeng, Dewen,Zhou, Hongyan,et al. Solubility of the Ternary System LiCl + NH4Cl + H2O[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2011,56(4):1096-1104.
APA Ouyang, Haitang,Zeng, Dewen,Zhou, Hongyan,Han, Haijun,&Yao, Yan.(2011).Solubility of the Ternary System LiCl + NH4Cl + H2O.JOURNAL OF CHEMICAL AND ENGINEERING DATA,56(4),1096-1104.
MLA Ouyang, Haitang,et al."Solubility of the Ternary System LiCl + NH4Cl + H2O".JOURNAL OF CHEMICAL AND ENGINEERING DATA 56.4(2011):1096-1104.
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