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题名: Tetranuclear mixed-valence Co(II/III) and binuclear Ni(II) complexesincorporating hydroxyl-rich ligand: Syntheses, structures and magneticproperties
作者: Zhang, Su-Yun ;  Zheng, Lina ;  Chen, Wenqian ;  Li, Yahong
刊名: INORGANICA CHIMICA ACTA
出版日期: 2011
卷号: 367, 期号:1, 页码:44-50
关键词: Tetranuclear clusters ;  Mixed-valence ;  Coordination mode ;  Binuclear
英文摘要: Three complexes of composition [(Co2Co2III)-Co-II(H(2)hbhpd)(2)(H(4)hbhpd)(2)(H2O)(2)]Cl-2(CH3OH)(4) (1), [(Co2Co2III)-Co-II (H(2)hbhpd)(2)(H(4)hbhpd)(2)(H2O)(2)](NO3)(2)(CH3OH)(4) (2) and [Ni-2(H(4)hbhpd)(2)(NO3)](NO3)(CH3OH)(1.5) (3) (H(5)hbhpd = 2-(2-hydroxy-benzylamino)-2-hydroxymethyl-propane-1,3-diol) have been synthesized and their structures have been characterized. Complexes 1 and 2 are mixed-valence cobalt clusters and display face-sharing monovacant dicubane structures. In the complexes 1 and 2, one of the three alkyl hydroxyl groups of H(5)hbhpd ligand is deprotonated instead of deprotonation of phenyl hydroxyl group; thus monoanionic H(4)hbhpd ligand displays novel eta(3), eta(1), eta(1), mu(3) coordination mode. Complex 3 is binuclear, and the two metal centers of 3 are bridged by two deprotonated phenyl hydroxyl oxygen atoms and iso-orthogonalized by a nitrato group in eta(1)eta(1)-O,O' coordination fashion. Variable-temperature solid-state dc magnetization studies have been performed in the temperature range 2-300 K for compounds 1 and 3. Antiferromagnetic interactions were determined for 1 and ferromagnetic couplings were found for 3. (C) 2010 Elsevier B.V. All rights reserved. Three complexes of composition [(Co2Co2III)-Co-II(H(2)hbhpd)(2)(H(4)hbhpd)(2)(H2O)(2)]Cl-2(CH3OH)(4) (1), [(Co2Co2III)-Co-II (H(2)hbhpd)(2)(H(4)hbhpd)(2)(H2O)(2)](NO3)(2)(CH3OH)(4) (2) and [Ni-2(H(4)hbhpd)(2)(NO3)](NO3)(CH3OH)(1.5) (3) (H(5)hbhpd = 2-(2-hydroxy-benzylamino)-2-hydroxymethyl-propane-1,3-diol) have been synthesized and their structures have been characterized. Complexes 1 and 2 are mixed-valence cobalt clusters and display face-sharing monovacant dicubane structures. In the complexes 1 and 2, one of the three alkyl hydroxyl groups of H(5)hbhpd ligand is deprotonated instead of deprotonation of phenyl hydroxyl group; thus monoanionic H(4)hbhpd ligand displays novel eta(3), eta(1), eta(1), mu(3) coordination mode. Complex 3 is binuclear, and the two metal centers of 3 are bridged by two deprotonated phenyl hydroxyl oxygen atoms and iso-orthogonalized by a nitrato group in eta(1)eta(1)-O,O' coordination fashion. Variable-temperature solid-state dc magnetization studies have been performed in the temperature range 2-300 K for compounds 1 and 3. Antiferromagnetic interactions were determined for 1 and ferromagnetic couplings were found for 3. (C) 2010 Elsevier B.V. All rights reserved.
收录类别: SCI
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.isl.ac.cn/handle/363002/1884
Appears in Collections:青海盐湖研究所知识仓储(2014年之前)_期刊论文

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Recommended Citation:
Zhang, Su-Yun,Zheng, Lina,Chen, Wenqian,et al. Tetranuclear mixed-valence Co(II/III) and binuclear Ni(II) complexesincorporating hydroxyl-rich ligand: Syntheses, structures and magneticproperties[J]. INORGANICA CHIMICA ACTA,2011,367(1):44-50.
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