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Physicochemical properties of ionic liquid analogue containing magnesiumchloride as temperature and composition dependence
Yue, Duyuan; Jing, Yan; Ma, Jun; Yao, Ying; Jia, Yongzhong
2012
发表期刊JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN1388-6150
卷号110期号:2页码:773-780
摘要The ionic liquid analogue containing MgCl2 based on choline chloride and glycerol was reported. The solubility of MgCl2 in the ionic liquid analogue based on choline chloride and glycerol was measured from T = 293-393 K. The empirical equation about the solubility and temperature was obtained. Thermal analysis showed that the ionic liquid analogue was stable from room temperature to 140 degrees C. The physical properties such as conductivity sigma, density rho and viscosity eta of ionic liquid analogue were measured as function of the content of MgCl2 and temperature. An empirical equation about the density (rho) and temperature was obtained. The ions transport behaviours are analyzed using hole-theory. It is shown that the conductivity of the ionic liquid analogues is controlled by the ion mobility and the suitable voids. The ionic liquid analogue containing MgCl2 based on choline chloride and glycerol was reported. The solubility of MgCl2 in the ionic liquid analogue based on choline chloride and glycerol was measured from T = 293-393 K. The empirical equation about the solubility and temperature was obtained. Thermal analysis showed that the ionic liquid analogue was stable from room temperature to 140 degrees C. The physical properties such as conductivity sigma, density rho and viscosity eta of ionic liquid analogue were measured as function of the content of MgCl2 and temperature. An empirical equation about the density (rho) and temperature was obtained. The ions transport behaviours are analyzed using hole-theory. It is shown that the conductivity of the ionic liquid analogues is controlled by the ion mobility and the suitable voids.
关键词Ionic Liquid Analogue Conductivity Viscosity Density Hole-theory
收录类别SCI
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/2019
专题青海盐湖研究所知识仓储
推荐引用方式
GB/T 7714
Yue, Duyuan,Jing, Yan,Ma, Jun,et al. Physicochemical properties of ionic liquid analogue containing magnesiumchloride as temperature and composition dependence[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2012,110(2):773-780.
APA Yue, Duyuan,Jing, Yan,Ma, Jun,Yao, Ying,&Jia, Yongzhong.(2012).Physicochemical properties of ionic liquid analogue containing magnesiumchloride as temperature and composition dependence.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,110(2),773-780.
MLA Yue, Duyuan,et al."Physicochemical properties of ionic liquid analogue containing magnesiumchloride as temperature and composition dependence".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 110.2(2012):773-780.
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