ISL OpenIR  > 青海盐湖研究所知识仓储
Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT
Li, Lei; Huang, Genping; Chen, Zhou; Liu, Wei; Wang, Xiufang; Chen, Yanmei; Yang, Lijuan; Li, Wu; Li, Yahong
2012
Source PublicationEUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN1434-193X
Issue28Pages:5564-5572
AbstractThe successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed. The successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed.
KeywordSynthetic Methods Hydroamination Gallium Alkynes Reaction
Indexed BySCI
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/2022
Collection青海盐湖研究所知识仓储
Recommended Citation
GB/T 7714
Li, Lei,Huang, Genping,Chen, Zhou,et al. Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(28):5564-5572.
APA Li, Lei.,Huang, Genping.,Chen, Zhou.,Liu, Wei.,Wang, Xiufang.,...&Li, Yahong.(2012).Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(28),5564-5572.
MLA Li, Lei,et al."Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .28(2012):5564-5572.
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