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Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT
Li, Lei; Huang, Genping; Chen, Zhou; Liu, Wei; Wang, Xiufang; Chen, Yanmei; Yang, Lijuan; Li, Wu; Li, Yahong
2012
发表期刊EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN1434-193X
期号28页码:5564-5572
摘要The successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed. The successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed.
关键词Synthetic Methods Hydroamination Gallium Alkynes Reaction
收录类别SCI
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/2022
专题青海盐湖研究所知识仓储
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Li, Lei,Huang, Genping,Chen, Zhou,et al. Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(28):5564-5572.
APA Li, Lei.,Huang, Genping.,Chen, Zhou.,Liu, Wei.,Wang, Xiufang.,...&Li, Yahong.(2012).Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(28),5564-5572.
MLA Li, Lei,et al."Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .28(2012):5564-5572.
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