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题名: Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT
作者: Li, Lei ;  Huang, Genping ;  Chen, Zhou ;  Liu, Wei ;  王秀芳 ;  Chen, Yanmei ;  Yang, Lijuan ;  李武 ;  Li, Yahong
刊名: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
出版日期: 2012
期号: 28, 页码:5564-5572
关键词: Synthetic methods ;  Hydroamination ;  Gallium ;  Alkynes ;  Reaction
英文摘要: The successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed. The successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed.
收录类别: SCI
Citation statistics: 
内容类型: 期刊论文
URI标识: http://ir.isl.ac.cn/handle/363002/2022
Appears in Collections:青海盐湖研究所知识仓储(2014年之前)_期刊论文

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Recommended Citation:
Li, Lei,Huang, Genping,Chen, Zhou,et al. Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(28):5564-5572.
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