Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT

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	Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT
	Li, Lei; Huang, Genping; Chen, Zhou; Liu, Wei; Wang, Xiufang; Chen, Yanmei; Yang, Lijuan; Li, Wu; Li, Yahong
	2012
发表期刊	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN	1434-193X
期号	28 页码:5564-5572
关键词	Synthetic Methods Hydroamination Gallium Alkynes Reaction
摘要	The successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed. The successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed.
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/2022
专题	青海盐湖研究所知识仓储
推荐引用方式 GB/T 7714	Li, Lei,Huang, Genping,Chen, Zhou,et al. Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(28):5564-5572.
APA	Li, Lei.,Huang, Genping.,Chen, Zhou.,Liu, Wei.,Wang, Xiufang.,...&Li, Yahong.(2012).Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(28),5564-5572.
MLA	Li, Lei,et al."Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope,Limitation, and Mechanistic Studies by DFT".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .28(2012):5564-5572.