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Structure and physico-chemical properties of three analogous ionicliquids containing magnesium chloride
Wang, Huaiyou; Jing, Yan; Wang, Xiaohua; Yao, Ying; Jia, Yongzhong
2012
发表期刊JOURNAL OF MOLECULAR LIQUIDS
ISSN0167-7322
卷号170期号:*页码:20-24
摘要Three analogous ionic liquids containing magnesium chloride (MgCl2) are reported. The structure of the analogous ionic liquid is preliminarily investigated by Fourier transform infrared spectroscopy (FTIR). The physicochemical properties of eutectic mixtures of choline chloride (ChCl)-MgCl2 and ethylene glycol (EG), glycerol (Gl) or urea such as viscosity, conductivity, density and CV are measured as a function of temperature at atmospheric pressure. From this variation with temperature, the thermal expansion coefficients (r), the molar Gibbs energy of activation (Delta G*) for viscous flow, the molar enthalpy of activation (Delta H*) and the molar entropy of activation (Delta S*) for viscous flow have been calculated. (C) 2012 Elsevier B.V. All rights reserved. Three analogous ionic liquids containing magnesium chloride (MgCl2) are reported. The structure of the analogous ionic liquid is preliminarily investigated by Fourier transform infrared spectroscopy (FTIR). The physicochemical properties of eutectic mixtures of choline chloride (ChCl)-MgCl2 and ethylene glycol (EG), glycerol (Gl) or urea such as viscosity, conductivity, density and CV are measured as a function of temperature at atmospheric pressure. From this variation with temperature, the thermal expansion coefficients (r), the molar Gibbs energy of activation (Delta G*) for viscous flow, the molar enthalpy of activation (Delta H*) and the molar entropy of activation (Delta S*) for viscous flow have been calculated. (C) 2012 Elsevier B.V. All rights reserved.
关键词Analogous Ionic Liquid Structure Viscosity Conductivity Cv
收录类别SCI
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/2049
专题青海盐湖研究所知识仓储
盐湖资源与化学实验室
推荐引用方式
GB/T 7714
Wang, Huaiyou,Jing, Yan,Wang, Xiaohua,et al. Structure and physico-chemical properties of three analogous ionicliquids containing magnesium chloride[J]. JOURNAL OF MOLECULAR LIQUIDS,2012,170(*):20-24.
APA Wang, Huaiyou,Jing, Yan,Wang, Xiaohua,Yao, Ying,&Jia, Yongzhong.(2012).Structure and physico-chemical properties of three analogous ionicliquids containing magnesium chloride.JOURNAL OF MOLECULAR LIQUIDS,170(*),20-24.
MLA Wang, Huaiyou,et al."Structure and physico-chemical properties of three analogous ionicliquids containing magnesium chloride".JOURNAL OF MOLECULAR LIQUIDS 170.*(2012):20-24.
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