Knowledge Management System Of Qinghai Institute of Salt Lakes,CAS
Structure and physico-chemical properties of three analogous ionicliquids containing magnesium chloride | |
Wang, Huaiyou![]() ![]() ![]() ![]() | |
2012 | |
发表期刊 | JOURNAL OF MOLECULAR LIQUIDS
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ISSN | 0167-7322 |
卷号 | 170期号:*页码:20-24 |
关键词 | Analogous Ionic Liquid Structure Viscosity Conductivity Cv |
摘要 | Three analogous ionic liquids containing magnesium chloride (MgCl2) are reported. The structure of the analogous ionic liquid is preliminarily investigated by Fourier transform infrared spectroscopy (FTIR). The physicochemical properties of eutectic mixtures of choline chloride (ChCl)-MgCl2 and ethylene glycol (EG), glycerol (Gl) or urea such as viscosity, conductivity, density and CV are measured as a function of temperature at atmospheric pressure. From this variation with temperature, the thermal expansion coefficients (r), the molar Gibbs energy of activation (Delta G*) for viscous flow, the molar enthalpy of activation (Delta H*) and the molar entropy of activation (Delta S*) for viscous flow have been calculated. (C) 2012 Elsevier B.V. All rights reserved. Three analogous ionic liquids containing magnesium chloride (MgCl2) are reported. The structure of the analogous ionic liquid is preliminarily investigated by Fourier transform infrared spectroscopy (FTIR). The physicochemical properties of eutectic mixtures of choline chloride (ChCl)-MgCl2 and ethylene glycol (EG), glycerol (Gl) or urea such as viscosity, conductivity, density and CV are measured as a function of temperature at atmospheric pressure. From this variation with temperature, the thermal expansion coefficients (r), the molar Gibbs energy of activation (Delta G*) for viscous flow, the molar enthalpy of activation (Delta H*) and the molar entropy of activation (Delta S*) for viscous flow have been calculated. (C) 2012 Elsevier B.V. All rights reserved. |
文献类型 | 期刊论文 |
条目标识符 | http://ir.isl.ac.cn/handle/363002/2049 |
专题 | 青海盐湖研究所知识仓储 盐湖资源与化学实验室 |
推荐引用方式 GB/T 7714 | Wang, Huaiyou,Jing, Yan,Wang, Xiaohua,et al. Structure and physico-chemical properties of three analogous ionicliquids containing magnesium chloride[J]. JOURNAL OF MOLECULAR LIQUIDS,2012,170(*):20-24. |
APA | Wang, Huaiyou,Jing, Yan,Wang, Xiaohua,Yao, Ying,&Jia, Yongzhong.(2012).Structure and physico-chemical properties of three analogous ionicliquids containing magnesium chloride.JOURNAL OF MOLECULAR LIQUIDS,170(*),20-24. |
MLA | Wang, Huaiyou,et al."Structure and physico-chemical properties of three analogous ionicliquids containing magnesium chloride".JOURNAL OF MOLECULAR LIQUIDS 170.*(2012):20-24. |
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