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题名: Co(II) and Ni(II) complexes incorporating N-acetimidoylacetamidineligand: Synthesis and structures
作者: Chen, Yanmei ;  胡斌 ;  Xu, Bin ;  Zhang, Suyun ;  Zhou, Fengying ;  Li, Yahong
刊名: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
出版日期: 2012
卷号: 57, 期号:3, 页码:386-389
英文摘要: Two new square planar complexes with the formula Co(L)(2) center dot CH3OH (1) and Ni(L)(2) center dot CH3OH (2) (HL = HN{C(Me)=NH}(2) = N-acetimidoylacetamidine) have been synthesized by solvothermal reactions in methanol/acetonitrile. N-acetimidoylacetamidine ligand was derived from the self-condensation reaction of acetonitrile, and the reaction was promoted by the cooperation of M(II) (M = Co in 1 and M = Ni in 2) with diphenylcarbazide. 1 and 2 are characterized by single crystal X-ray diffraction, elemental analysis and infrared spectrum. Both complexes crystallize in the monoclinic space group P2(1)/c with a = 9.329(6) , b = 11.494(7) , c = 13.040(8) , beta = 92.945(11)A degrees, V = 1396.3(16) (3) and Z = 4 for 1, and a = 9.323(4), b = 11.512(5) , c = 13.020(6), beta = 92.819(7)A degrees, V = 1395.7(10)(3) and Z = 4 for 2. Two new square planar complexes with the formula Co(L)(2) center dot CH3OH (1) and Ni(L)(2) center dot CH3OH (2) (HL = HN{C(Me)=NH}(2) = N-acetimidoylacetamidine) have been synthesized by solvothermal reactions in methanol/acetonitrile. N-acetimidoylacetamidine ligand was derived from the self-condensation reaction of acetonitrile, and the reaction was promoted by the cooperation of M(II) (M = Co in 1 and M = Ni in 2) with diphenylcarbazide. 1 and 2 are characterized by single crystal X-ray diffraction, elemental analysis and infrared spectrum. Both complexes crystallize in the monoclinic space group P2(1)/c with a = 9.329(6) , b = 11.494(7) , c = 13.040(8) , beta = 92.945(11)A degrees, V = 1396.3(16) (3) and Z = 4 for 1, and a = 9.323(4), b = 11.512(5) , c = 13.020(6), beta = 92.819(7)A degrees, V = 1395.7(10)(3) and Z = 4 for 2.
收录类别: SCI
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内容类型: 期刊论文
URI标识: http://ir.isl.ac.cn/handle/363002/2067
Appears in Collections:青海盐湖研究所知识仓储(2014年之前)_期刊论文

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Recommended Citation:
Chen, Yanmei,Hu, Bin,Xu, Bin,et al. Co(II) and Ni(II) complexes incorporating N-acetimidoylacetamidineligand: Synthesis and structures[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2012,57(3):386-389.
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