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A unique tetranuclear cubane-like [Ni4O4] complex supported byhydroxyl-rich ligands: Synthesis, crystal structure and magneticproperty
Zhang, Su-Yun; Chen, Wen-Qian; Hu, Bin; Chen, Yan-Mei; Li, Wu; Li, Yahong
2012
发表期刊INORGANIC CHEMISTRY COMMUNICATIONS
ISSN1387-7003
卷号16页码:74-77
摘要The tetranuclear cubane-like complex of the formula [Ni-4(HL1)(3)(HL2)(H2O)(CH3OH)] [CH3COO]center dot 2CH(3)OH center dot CH3CN (1) (H(3)L1=3-(2-hydroxybenzylideneamino)propane-1,2-diol; H(2)L2=3-aminoprppane-1,2-diol) has been prepared by a one-pot reaction of nickel(II) acetate, salicylaldehyde and 3-aminopropane-1,2-diol, where the H(3)L1 ligand was generated in situ via the condensation reaction between salicylaldehyde and 3-aminopropane-1,2-diol. The X-ray diffraction analysis of the complex showed a Ni4O4 cubane arrangement and the coordination environments of four Ni(II) ions are different from each other. Magnetic studies indicated ferromagnetic behavior for the complex. The magnetic data were fitted and the parameters were given as g=2.43, J(1)=15.96, and J(2)=4.116. (C) 2011 Elsevier B.V. All rights reserved. The tetranuclear cubane-like complex of the formula [Ni-4(HL1)(3)(HL2)(H2O)(CH3OH)] [CH3COO]center dot 2CH(3)OH center dot CH3CN (1) (H(3)L1=3-(2-hydroxybenzylideneamino)propane-1,2-diol; H(2)L2=3-aminoprppane-1,2-diol) has been prepared by a one-pot reaction of nickel(II) acetate, salicylaldehyde and 3-aminopropane-1,2-diol, where the H(3)L1 ligand was generated in situ via the condensation reaction between salicylaldehyde and 3-aminopropane-1,2-diol. The X-ray diffraction analysis of the complex showed a Ni4O4 cubane arrangement and the coordination environments of four Ni(II) ions are different from each other. Magnetic studies indicated ferromagnetic behavior for the complex. The magnetic data were fitted and the parameters were given as g=2.43, J(1)=15.96, and J(2)=4.116. (C) 2011 Elsevier B.V. All rights reserved.
关键词Tetranuclear Cubane-like Nickel Complex Magnetic Properties
收录类别SCI
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/2075
专题青海盐湖研究所知识仓储
推荐引用方式
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Zhang, Su-Yun,Chen, Wen-Qian,Hu, Bin,et al. A unique tetranuclear cubane-like [Ni4O4] complex supported byhydroxyl-rich ligands: Synthesis, crystal structure and magneticproperty[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2012,16:74-77.
APA Zhang, Su-Yun,Chen, Wen-Qian,Hu, Bin,Chen, Yan-Mei,Li, Wu,&Li, Yahong.(2012).A unique tetranuclear cubane-like [Ni4O4] complex supported byhydroxyl-rich ligands: Synthesis, crystal structure and magneticproperty.INORGANIC CHEMISTRY COMMUNICATIONS,16,74-77.
MLA Zhang, Su-Yun,et al."A unique tetranuclear cubane-like [Ni4O4] complex supported byhydroxyl-rich ligands: Synthesis, crystal structure and magneticproperty".INORGANIC CHEMISTRY COMMUNICATIONS 16(2012):74-77.
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