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题名: Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures
作者: Chen, Wenqian ;  Chen, Yanmei ;  Liu, Wei ;  Lei, Tao ;  Gao, Qian ;  Kim, Damin ;  Su, David ;  李武 ;  Li, Yahong
刊名: JOURNAL OF COORDINATION CHEMISTRY
出版日期: 2012
卷号: 65, 期号:24, 页码:4430-4440
关键词: Schiff-base phthalen-ol ;  Lanthanide complexes ;  Crystal structure
英文摘要: Reaction of Ln(NO3)3?.?6H2O with H2napn (H2napn?=?N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H2napn)(SCN)(C2H5OH)2(NO3)2] n (1), [La(H2napn)2(SCN)(NO3)2] n (2), and [Ln(H2napn)1.5(NO3)3] n [Ln?=?La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H2napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (27) with lanthanides. Each metal center of 17 is nine-coordinate. Lanthanide contraction is observed in 37. Reaction of Ln(NO3)3?.?6H2O with H2napn (H2napn?=?N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H2napn)(SCN)(C2H5OH)2(NO3)2] n (1), [La(H2napn)2(SCN)(NO3)2] n (2), and [Ln(H2napn)1.5(NO3)3] n [Ln?=?La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H2napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (27) with lanthanides. Each metal center of 17 is nine-coordinate. Lanthanide contraction is observed in 37.
收录类别: SCI
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内容类型: 期刊论文
URI标识: http://ir.isl.ac.cn/handle/363002/2076
Appears in Collections:青海盐湖研究所知识仓储(2014年之前)_期刊论文

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Recommended Citation:
Chen, Wenqian,Chen, Yanmei,Liu, Wei,et al. Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures[J]. JOURNAL OF COORDINATION CHEMISTRY,2012,65(24):4430-4440.
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