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Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures
Chen, Wenqian; Chen, Yanmei; Liu, Wei; Lei, Tao; Gao, Qian; Kim, Damin; Su, David; Li, Wu; Li, Yahong
2012
Source PublicationJOURNAL OF COORDINATION CHEMISTRY
ISSN0095-8972
Volume65Issue:24Pages:4430-4440
AbstractReaction of Ln(NO3)3?.?6H2O with H2napn (H2napn?=?N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H2napn)(SCN)(C2H5OH)2(NO3)2] n (1), [La(H2napn)2(SCN)(NO3)2] n (2), and [Ln(H2napn)1.5(NO3)3] n [Ln?=?La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H2napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (27) with lanthanides. Each metal center of 17 is nine-coordinate. Lanthanide contraction is observed in 37. Reaction of Ln(NO3)3?.?6H2O with H2napn (H2napn?=?N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H2napn)(SCN)(C2H5OH)2(NO3)2] n (1), [La(H2napn)2(SCN)(NO3)2] n (2), and [Ln(H2napn)1.5(NO3)3] n [Ln?=?La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H2napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (27) with lanthanides. Each metal center of 17 is nine-coordinate. Lanthanide contraction is observed in 37.
KeywordSchiff-base Phthalen-ol Lanthanide Complexes Crystal Structure
Indexed BySCI
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/2076
Collection青海盐湖研究所知识仓储
Recommended Citation
GB/T 7714
Chen, Wenqian,Chen, Yanmei,Liu, Wei,et al. Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures[J]. JOURNAL OF COORDINATION CHEMISTRY,2012,65(24):4430-4440.
APA Chen, Wenqian.,Chen, Yanmei.,Liu, Wei.,Lei, Tao.,Gao, Qian.,...&Li, Yahong.(2012).Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures.JOURNAL OF COORDINATION CHEMISTRY,65(24),4430-4440.
MLA Chen, Wenqian,et al."Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures".JOURNAL OF COORDINATION CHEMISTRY 65.24(2012):4430-4440.
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