Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures

ISL OpenIR > 青海盐湖研究所知识仓储

	Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures
	Chen, Wenqian; Chen, Yanmei; Liu, Wei; Lei, Tao; Gao, Qian; Kim, Damin; Su, David; Li, Wu; Li, Yahong
	2012
发表期刊	JOURNAL OF COORDINATION CHEMISTRY
ISSN	0095-8972
卷号	65 期号:24 页码:4430-4440
关键词	Schiff-base Phthalen-ol Lanthanide Complexes Crystal Structure
摘要	Reaction of Ln(NO3)3?.?6H2O with H2napn (H2napn?=?N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H2napn)(SCN)(C2H5OH)2(NO3)2] n (1), [La(H2napn)2(SCN)(NO3)2] n (2), and [Ln(H2napn)1.5(NO3)3] n [Ln?=?La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H2napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (27) with lanthanides. Each metal center of 17 is nine-coordinate. Lanthanide contraction is observed in 37. Reaction of Ln(NO3)3?.?6H2O with H2napn (H2napn?=?N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato)) and KSCN produces seven new coordination polymers, [La(H2napn)(SCN)(C2H5OH)2(NO3)2] n (1), [La(H2napn)2(SCN)(NO3)2] n (2), and [Ln(H2napn)1.5(NO3)3] n [Ln?=?La(3), Sm(4), Eu(5), Dy(6), Er(7)]. Crystal structure analysis reveals that H2napn functions as a bridging ligand, forming a 1-D chain polymer (1) and 2-D open-frameworks (27) with lanthanides. Each metal center of 17 is nine-coordinate. Lanthanide contraction is observed in 37.
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/2076
专题	青海盐湖研究所知识仓储
推荐引用方式 GB/T 7714	Chen, Wenqian,Chen, Yanmei,Liu, Wei,et al. Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures[J]. JOURNAL OF COORDINATION CHEMISTRY,2012,65(24):4430-4440.
APA	Chen, Wenqian.,Chen, Yanmei.,Liu, Wei.,Lei, Tao.,Gao, Qian.,...&Li, Yahong.(2012).Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures.JOURNAL OF COORDINATION CHEMISTRY,65(24),4430-4440.
MLA	Chen, Wenqian,et al."Coordination polymers of lanthanides incorporating N,N'-ethylenebis(2-hydroxy-1-naphthylideneiminato): syntheses and crystalstructures".JOURNAL OF COORDINATION CHEMISTRY 65.24(2012):4430-4440.

条目包含的文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
00958972.2012.744002（923KB）			开放获取	CC BY-NC-SA	浏览请求全文