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题名: A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear coppercomplex incorporating a hydroxyl-rich ligand: syntheses and crystalstructures
作者: Zhang, Suyun ;  Chen, Wenqian ;  胡斌 ;  Chen, Yanmei ;  Zheng, Lina ;  Li, Yahong ;  李武
刊名: JOURNAL OF COORDINATION CHEMISTRY
出版日期: 2012
卷号: 65, 期号:23, 页码:4147-4155
关键词: Tetranuclear ;  Cubane-like ;  Nickel ;  Copper
英文摘要: A tetranuclear cubane-like cluster [Ni-4(HL)(4)(DMSO)(2)] center dot 2DMSO center dot H2O (1) and a dinuclear compound [Cu2Cl2(H2L)(2)] center dot 1.5MeOH (2) (H3L = 3-(2-hydroxy-benzylideneamino)propane-1,2-diol) have been prepared and characterized by X-ray single crystal diffraction, IR, and elemental analysis. The X-ray diffraction analysis indicated that the four metals of 1 showed a Ni4O4 cubane arrangement, and two of the six faces of the Ni4O4 cubane were capped by DMSO. Complex 1 is the first reported DMSO capped Ni4O4 cubane cluster. Complex 2 contains a u(2)-Cl bridged dinuclear core with each Cu-II ion exhibiting pseudo square pyramidal geometry. A tetranuclear cubane-like cluster [Ni-4(HL)(4)(DMSO)(2)] center dot 2DMSO center dot H2O (1) and a dinuclear compound [Cu2Cl2(H2L)(2)] center dot 1.5MeOH (2) (H3L = 3-(2-hydroxy-benzylideneamino)propane-1,2-diol) have been prepared and characterized by X-ray single crystal diffraction, IR, and elemental analysis. The X-ray diffraction analysis indicated that the four metals of 1 showed a Ni4O4 cubane arrangement, and two of the six faces of the Ni4O4 cubane were capped by DMSO. Complex 1 is the first reported DMSO capped Ni4O4 cubane cluster. Complex 2 contains a u(2)-Cl bridged dinuclear core with each Cu-II ion exhibiting pseudo square pyramidal geometry.
收录类别: SCI
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内容类型: 期刊论文
URI标识: http://ir.isl.ac.cn/handle/363002/2078
Appears in Collections:青海盐湖研究所知识仓储(2014年之前)_期刊论文

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Recommended Citation:
Zhang, Suyun,Chen, Wenqian,Hu, Bin,et al. A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear coppercomplex incorporating a hydroxyl-rich ligand: syntheses and crystalstructures[J]. JOURNAL OF COORDINATION CHEMISTRY,2012,65(23):4147-4155.
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