A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear coppercomplex incorporating a hydroxyl-rich ligand: syntheses and crystalstructures

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	A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear coppercomplex incorporating a hydroxyl-rich ligand: syntheses and crystalstructures
	Zhang, Suyun; Chen, Wenqian; Hu, Bin; Chen, Yanmei; Zheng, Lina; Li, Yahong; Li, Wu
	2012
发表期刊	JOURNAL OF COORDINATION CHEMISTRY
ISSN	0095-8972
卷号	65 期号:23 页码:4147-4155
关键词	Tetranuclear Cubane-like Nickel Copper
摘要	A tetranuclear cubane-like cluster [Ni-4(HL)(4)(DMSO)(2)] center dot 2DMSO center dot H2O (1) and a dinuclear compound [Cu2Cl2(H2L)(2)] center dot 1.5MeOH (2) (H3L = 3-(2-hydroxy-benzylideneamino)propane-1,2-diol) have been prepared and characterized by X-ray single crystal diffraction, IR, and elemental analysis. The X-ray diffraction analysis indicated that the four metals of 1 showed a Ni4O4 cubane arrangement, and two of the six faces of the Ni4O4 cubane were capped by DMSO. Complex 1 is the first reported DMSO capped Ni4O4 cubane cluster. Complex 2 contains a u(2)-Cl bridged dinuclear core with each Cu-II ion exhibiting pseudo square pyramidal geometry. A tetranuclear cubane-like cluster [Ni-4(HL)(4)(DMSO)(2)] center dot 2DMSO center dot H2O (1) and a dinuclear compound [Cu2Cl2(H2L)(2)] center dot 1.5MeOH (2) (H3L = 3-(2-hydroxy-benzylideneamino)propane-1,2-diol) have been prepared and characterized by X-ray single crystal diffraction, IR, and elemental analysis. The X-ray diffraction analysis indicated that the four metals of 1 showed a Ni4O4 cubane arrangement, and two of the six faces of the Ni4O4 cubane were capped by DMSO. Complex 1 is the first reported DMSO capped Ni4O4 cubane cluster. Complex 2 contains a u(2)-Cl bridged dinuclear core with each Cu-II ion exhibiting pseudo square pyramidal geometry.
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/2078
专题	青海盐湖研究所知识仓储
推荐引用方式 GB/T 7714	Zhang, Suyun,Chen, Wenqian,Hu, Bin,et al. A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear coppercomplex incorporating a hydroxyl-rich ligand: syntheses and crystalstructures[J]. JOURNAL OF COORDINATION CHEMISTRY,2012,65(23):4147-4155.
APA	Zhang, Suyun.,Chen, Wenqian.,Hu, Bin.,Chen, Yanmei.,Zheng, Lina.,...&Li, Wu.(2012).A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear coppercomplex incorporating a hydroxyl-rich ligand: syntheses and crystalstructures.JOURNAL OF COORDINATION CHEMISTRY,65(23),4147-4155.
MLA	Zhang, Suyun,et al."A cubane-like [Ni4O4] cluster and a chloro-bridged dinuclear coppercomplex incorporating a hydroxyl-rich ligand: syntheses and crystalstructures".JOURNAL OF COORDINATION CHEMISTRY 65.23(2012):4147-4155.

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