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Rubidium and cesium ion adsorption by an ammoniummolybdophosphate-calcium alginate composite adsorbent
Ye, Xiushen; Wu, Zhijian; Li, Wu; Liu, Haining; Li, Quan; Qing, Binju; Guo, Min; Go, Fei
2009
发表期刊COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
ISSN0927-7757
卷号342期号:1-3页码:76-83
产权排序SCI
关键词Rubidium Cesium Adsorption Ammonium Molybdophosphate Composite
语种A composite spherical adsorbent was prepared with ammonium molybdophosphate (AMP), sodium alginate (NaALG), and calcium chloride. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to characterize the composite adsorbent. The adsorption of rubidium and cesium ions onto the composite adsorbent in aqueous solutions was investigated comprehensively by varying the initial metal ion concentration, pH, ionic strength, and temperature. The adsorption kinetics of both rubidium and cesium was described by the first-order and second-order kinetic models. The second-order rate constant and the initial adsorption rate increase with increasing temperature. In general, the equilibrium adsorption amount of both rubidium and cesium increases with the increase in initial metal ion concentration, but decreases with increasing ionic strength and temperature. Maximum adsorption of rubidium and cesium Occurs in the solution with an equilibrium pH Value of 3.5-4.5. Under similar conditions, cesium shows a higher adsorption amount than rubidium. The composite adsorbent is easy to prepare and highly porous. It has a fast adsorption rate and ail adsorption capacity of 0.58 and 0.69 mmol g(-1) for rubidium and cesium, respectively. The composite adsorbent is effective for the adsorption of rubidium or cesium ions from Solutions containing some other alkali metal ions, Such as sodium ions. (c) 2009 Elsevier B.V. All rights reserved. A composite spherical adsorbent was prepared with ammonium molybdophosphate (AMP), sodium alginate (NaALG), and calcium chloride. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) were used to characterize the composite adsorbent. The adsorption of rubidium and cesium ions onto the composite adsorbent in aqueous solutions was investigated comprehensively by varying the initial metal ion concentration, pH, ionic strength, and temperature. The adsorption kinetics of both rubidium and cesium was described by the first-order and second-order kinetic models. The second-order rate constant and the initial adsorption rate increase with increasing temperature. In general, the equilibrium adsorption amount of both rubidium and cesium increases with the increase in initial metal ion concentration, but decreases with increasing ionic strength and temperature. Maximum adsorption of rubidium and cesium Occurs in the solution with an equilibrium pH Value of 3.5-4.5. Under similar conditions, cesium shows a higher adsorption amount than rubidium. The composite adsorbent is easy to prepare and highly porous. It has a fast adsorption rate and ail adsorption capacity of 0.58 and 0.69 mmol g(-1) for rubidium and cesium, respectively. The composite adsorbent is effective for the adsorption of rubidium or cesium ions from Solutions containing some other alkali metal ions, Such as sodium ions. (c) 2009 Elsevier B.V. All rights reserved.
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/2103
专题青海盐湖研究所知识仓储
盐湖资源与化学实验室
科研管理、支撑部门
推荐引用方式
GB/T 7714
Ye, Xiushen,Wu, Zhijian,Li, Wu,et al. Rubidium and cesium ion adsorption by an ammoniummolybdophosphate-calcium alginate composite adsorbent[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2009,342(1-3):76-83.
APA Ye, Xiushen.,Wu, Zhijian.,Li, Wu.,Liu, Haining.,Li, Quan.,...&Go, Fei.(2009).Rubidium and cesium ion adsorption by an ammoniummolybdophosphate-calcium alginate composite adsorbent.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,342(1-3),76-83.
MLA Ye, Xiushen,et al."Rubidium and cesium ion adsorption by an ammoniummolybdophosphate-calcium alginate composite adsorbent".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 342.1-3(2009):76-83.
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