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题名: Effects of pitzer mixing parameters on the solubility prediction ofHCl-RbCl-H2O system at 25 degrees C
作者: Pan, H.Song, P.Han, Z.Li, Y.Li, WuXia, S.
刊名: RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
出版日期: 2007
卷号: 52, 期号:11, 页码:1803-1807
中文摘要: The calculated solubilities of the phase system HCl-RbCl-H2O at 25 degrees C when the Pitzer's mixing parameters theta(HRb) and psi(HRbCl) are changed by +10% and -10% are reported. The calculated results indicate that there is a great deviation between the experimental data and the calculated solubilities when the mixing parameters were varied. The influence of psi(RbHCl) in solubility prediction in the RbCl-HCl-H2O system is much stronger than that of theta(RbH). This study supplies a theoretical basis for the manufacturing process which was proposed by Gao and employed to extract LiCl, RbCl, and CsCl from salt lake brine. The calculated solubilities of the phase system HCl-RbCl-H2O at 25 degrees C when the Pitzer's mixing parameters theta(HRb) and psi(HRbCl) are changed by +10% and -10% are reported. The calculated results indicate that there is a great deviation between the experimental data and the calculated solubilities when the mixing parameters were varied. The influence of psi(RbHCl) in solubility prediction in the RbCl-HCl-H2O system is much stronger than that of theta(RbH). This study supplies a theoretical basis for the manufacturing process which was proposed by Gao and employed to extract LiCl, RbCl, and CsCl from salt lake brine.
英文摘要: 英文摘要
收录类别: SCI
Citation statistics: 
内容类型: 期刊论文
URI标识: http://ir.isl.ac.cn/handle/363002/2280
Appears in Collections:青海盐湖研究所知识仓储(2014年之前)_期刊论文

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Recommended Citation:
Pan, H.Song, P.Han, Z.Li, Y.Li, WuXia, S.. Effects of pitzer mixing parameters on the solubility prediction ofHCl-RbCl-H2O system at 25 degrees C[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2007,52(11):1803-1807.
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