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Effects of pitzer mixing parameters on the solubility prediction ofHCl-RbCl-H2O system at 25 degrees C
Pan, H.Song, P.Han, Z.Li, Y.Li, WuXia, S.
2007
发表期刊RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN0036-0236
卷号52期号:11页码:1803-1807
摘要The calculated solubilities of the phase system HCl-RbCl-H2O at 25 degrees C when the Pitzer's mixing parameters theta(HRb) and psi(HRbCl) are changed by +10% and -10% are reported. The calculated results indicate that there is a great deviation between the experimental data and the calculated solubilities when the mixing parameters were varied. The influence of psi(RbHCl) in solubility prediction in the RbCl-HCl-H2O system is much stronger than that of theta(RbH). This study supplies a theoretical basis for the manufacturing process which was proposed by Gao and employed to extract LiCl, RbCl, and CsCl from salt lake brine. The calculated solubilities of the phase system HCl-RbCl-H2O at 25 degrees C when the Pitzer's mixing parameters theta(HRb) and psi(HRbCl) are changed by +10% and -10% are reported. The calculated results indicate that there is a great deviation between the experimental data and the calculated solubilities when the mixing parameters were varied. The influence of psi(RbHCl) in solubility prediction in the RbCl-HCl-H2O system is much stronger than that of theta(RbH). This study supplies a theoretical basis for the manufacturing process which was proposed by Gao and employed to extract LiCl, RbCl, and CsCl from salt lake brine.
其他摘要英文摘要
收录类别SCI
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/2280
专题青海盐湖研究所知识仓储
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Pan, H.Song, P.Han, Z.Li, Y.Li, WuXia, S.. Effects of pitzer mixing parameters on the solubility prediction ofHCl-RbCl-H2O system at 25 degrees C[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2007,52(11):1803-1807.
APA Pan, H.Song, P.Han, Z.Li, Y.Li, WuXia, S..(2007).Effects of pitzer mixing parameters on the solubility prediction ofHCl-RbCl-H2O system at 25 degrees C.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,52(11),1803-1807.
MLA Pan, H.Song, P.Han, Z.Li, Y.Li, WuXia, S.."Effects of pitzer mixing parameters on the solubility prediction ofHCl-RbCl-H2O system at 25 degrees C".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 52.11(2007):1803-1807.
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