中国科学院青海盐湖研究所机构知识库
Advanced  
ISL OpenIR  > 青海盐湖研究所知识仓储  > 期刊论文
题名: An unexpected role of a trace amount of water in catalyzing protontransfer in phosphine-catalyzed (3+2) cycloaddition of allenoates andalkenes
作者: Xia, Yuanzhi ;  Liang, YongChen, YuanyuanWang, Ming ;  Jiao, Lei ;  Huang, Feng ;  Liu, Song ;  Li, Yahong ;  Yu, Zhi-Xiang
刊名: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
出版日期: 2007
卷号: 129, 期号:12, 页码:3470- +
中文摘要: Through the joint forces of computation and experiment, the detailed mechanism of the Lu phosphine catalyzed (3 + 2) cycloaddition of allenoates and alkenes has been elucidated. The overall potential energy surface of the Lu (3 + 2) reaction has been computed. More importantly, theory and experiment have confirmed that a trace amount of water plays a critical role in assisting the process of [1,2] proton shift in the Lu reaction. Through the joint forces of computation and experiment, the detailed mechanism of the Lu phosphine catalyzed (3 + 2) cycloaddition of allenoates and alkenes has been elucidated. The overall potential energy surface of the Lu (3 + 2) reaction has been computed. More importantly, theory and experiment have confirmed that a trace amount of water plays a critical role in assisting the process of [1,2] proton shift in the Lu reaction.
英文摘要: 英文摘要
收录类别: SCI
语种: 英语
Citation statistics: 
内容类型: 期刊论文
URI标识: http://ir.isl.ac.cn/handle/363002/2292
Appears in Collections:青海盐湖研究所知识仓储(2014年之前)_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
ja068215h[1].pdf(326KB)----开放获取
by-nc-sa
View Download

Recommended Citation:
Xia, Yuanzhi,Liang, YongChen, YuanyuanWang, Ming,Jiao, Lei,et al. An unexpected role of a trace amount of water in catalyzing protontransfer in phosphine-catalyzed (3+2) cycloaddition of allenoates andalkenes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2007,129(12):3470- +.
Service
 Recommend this item
 Sava as my favorate item
 Show this item's statistics
 Export Endnote File
Google Scholar
 Similar articles in Google Scholar
 [Xia, Yuanzhi]'s Articles
 [Liang, YongChen, YuanyuanWang, Ming]'s Articles
 [Jiao, Lei]'s Articles
CSDL cross search
 Similar articles in CSDL Cross Search
 [Xia, Yuanzhi]‘s Articles
 [Liang, YongChen, YuanyuanWang, Ming]‘s Articles
 [Jiao, Lei]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
  Add to CiteULike  Add to Connotea  Add to Del.icio.us  Add to Digg  Add to Reddit 
文件名: ja068215h[1].pdf
格式: Adobe PDF
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Copyright © 2007-2016  中国科学院青海盐湖研究所 - Feedback
Powered by CSpace