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An unexpected role of a trace amount of water in catalyzing protontransfer in phosphine-catalyzed (3+2) cycloaddition of allenoates andalkenes
Xia, Yuanzhi; Liang, YongChen, YuanyuanWang, Ming; Jiao, Lei; Huang, Feng; Liu, Song; Li, Yahong; Yu, Zhi-Xiang
2007
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
ISSN0002-7863
Volume129Issue:12Pages:3470- +
AbstractThrough the joint forces of computation and experiment, the detailed mechanism of the Lu phosphine catalyzed (3 + 2) cycloaddition of allenoates and alkenes has been elucidated. The overall potential energy surface of the Lu (3 + 2) reaction has been computed. More importantly, theory and experiment have confirmed that a trace amount of water plays a critical role in assisting the process of [1,2] proton shift in the Lu reaction. Through the joint forces of computation and experiment, the detailed mechanism of the Lu phosphine catalyzed (3 + 2) cycloaddition of allenoates and alkenes has been elucidated. The overall potential energy surface of the Lu (3 + 2) reaction has been computed. More importantly, theory and experiment have confirmed that a trace amount of water plays a critical role in assisting the process of [1,2] proton shift in the Lu reaction.
Other Abstract英文摘要
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/2292
Collection青海盐湖研究所知识仓储
Recommended Citation
GB/T 7714
Xia, Yuanzhi,Liang, YongChen, YuanyuanWang, Ming,Jiao, Lei,et al. An unexpected role of a trace amount of water in catalyzing protontransfer in phosphine-catalyzed (3+2) cycloaddition of allenoates andalkenes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2007,129(12):3470- +.
APA Xia, Yuanzhi.,Liang, YongChen, YuanyuanWang, Ming.,Jiao, Lei.,Huang, Feng.,Liu, Song.,...&Yu, Zhi-Xiang.(2007).An unexpected role of a trace amount of water in catalyzing protontransfer in phosphine-catalyzed (3+2) cycloaddition of allenoates andalkenes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,129(12),3470- +.
MLA Xia, Yuanzhi,et al."An unexpected role of a trace amount of water in catalyzing protontransfer in phosphine-catalyzed (3+2) cycloaddition of allenoates andalkenes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129.12(2007):3470- +.
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